RUI: New Catalytic Materials for Hydrodesulfurization Catalysis - Metal Borides and Phosphides

RUI：加氢脱硫催化新材料——金属硼化物和磷化物

• 批准号: 0101690
• 负责人: Mark Bussell
• 金额: $ 21.29万
• 依托单位: Western Washington University
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2001
• 资助国家: 美国
• 起止时间: 2001-04-15 至 2005-03-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0101690&HistoricalAwards=false
• 关键词: RUI; New; Catalytic; Materials; Hydrodesulfurization

This Research in Undergraduate Institution project at Western Washington University, a renewal of an earlier award, is to synthesize and characterize metal oxide-supported boride and phosphide catalysts to remove sulfur from organic sulfur compounds by hydrodesulfurization. This interdisciplinary project is jointly supported by the Advanced Materials and Processing Program in the Chemistry Division of the Mathematical and Physical Sciences Directorate and the Kinetics, Catalysis and Molecular Processes Program in the Division of Chemical Transport Systems of the Engineering Directorate. Professor Bussell and his students will prepare novel catalysts based on borides and phosphides of cobalt, nickel and molybdenum, and they will characterize them to optimize the catalyst synthesis and to determine the relationship between surface chemistries and catalytic properties. The research will introduce undergraduate and masters degree students to state of the art techniques in materials and surface chemistries, and will provide training to them in synthetic methods to prepare novel materials for heterogeneous catalysis. This award will provide fundamental information for the design, synthesis, characterization and application of novel bimetallic systems for hydrodesulfurization by heterogeneous catalysis. Metal oxide based borides and phosphides of nickel, cobalt and molybdenum will be prepared and evaluated for the removal of sulfur from organosulfur compound for potential application in the removal of sulfur from crude oil and coal. In addition, the research program will provide a rich multidisciplinary education and training opportunity to undergraduate and masters degree students in material and surface chemistries.

这项在西部华盛顿大学的本科机构项目的研究是较早的奖项，是为了合成和表征金属氧化物支持的硼化物和磷化物催化剂，以通过氢化硫化从有机硫化合物中去除硫。 该跨学科项目由数学和物理科学局的化学部门的高级材料和加工计划共同支持，以及工程局化学运输系统部的动力学，催化和分子过程计划。 Bussell教授和他的学生将根据钴，镍和钼的硼化物和磷化物制备新型催化剂，它们将其特征以优化催化剂合成并确定表面化学和催化性能之间的关系。 这项研究将向本科生和硕士学位的学生介绍材料和表面化学的最先进技术，并将通过合成方法为他们提供培训，以准备新的材料以进行异质催化。 该奖项将为新型双金属系统的设计，合成，表征和应用提供基本信息，以通过异质催化为氢化硫化。 将准备并评估镍，钴和钼的金属氧化物和磷化物，以从Organosulfur化合物中去除硫，以便在从原油和煤中去除硫的硫。此外，该研究计划将为本科和硕士学位的学生提供丰富的跨学科教育和培训机会。