U.S.-France Cooperative Research: Studies of Model C-H Bond and Si-H Bond Activation Processes on the Surfaces of Large[RG]n and [CH4]n Clusters
美法合作研究:大[RG]n和[CH4]n团簇表面模型C-H键和Si-H键活化过程的研究
基本信息
- 批准号:0124920
- 负责人:
- 金额:$ 1.8万
- 依托单位:
- 依托单位国家:美国
- 项目类别:Standard Grant
- 财政年份:2002
- 资助国家:美国
- 起止时间:2002-03-15 至 2005-02-28
- 项目状态:已结题
- 来源:
- 关键词:
项目摘要
0124920BreckenridgeThis three-year award for US-France collaboration in experimental physical chemistry involves researchers and students at the University of Utah and the Center for Atomic Energy (CEN) in Saclay, France. The principal investigators, William H. Breckenridge in the US, and Benoit Soep and Jean-Michel Mestdagh in France, lead this collaboration. They will study reactions of excited atoms and metal oxides produced at the surface in order to activate C-H (carbon-hydrogen) bonds. Activation of C-H bonds is important in a wide variety of technological processes such as hydrocarbon cracking, synthesis of chemicals from natural gas, hydrogenation, and organic synthesis. Many of these processes are either extremely complex chemically or occur under conditions which make it difficult to characterize and identify the processes responsible for bond breaking. The collaboration and comparison of experimental results will elucidate the bond-breaking process and understanding of how C-H activation occurs in these technological systems. Experiments will be performed at the University of Utah and in Saclay, France. The French group will conduct photosensitized C-H bond activation "surface" model experiments. These are complemented by metal oxide/methane experiments at the University of Utah. The collaboration and comparison of experimental results will elucidate the bond-breaking process and advance understanding of how C-H activation occurs in these technological systems. Graduate students will benefit through advanced training and participation in the collaborative experiments performed by an international team. This award represents the US side of parallel proposals to the NSF and the CNRS. NSF will cover travel funds and living expenses for the US investigator and his students. The CNRS will support visits by French researchers and students to the United States.
这项为期三年的美法实验物理化学合作奖涉及犹他大学和法国萨克莱原子能中心的研究人员和学生。主要研究人员,美国的William H. Breckenridge和法国的Benoit Soep和Jean-Michel Mestdagh领导了这次合作。他们将研究激发原子和表面产生的金属氧化物的反应,以激活碳氢键。C-H键的活化在许多技术过程中都很重要,比如碳氢化合物裂解、天然气合成、氢化和有机合成。这些过程中的许多要么在化学上极其复杂,要么在难以表征和识别导致断键的过程的条件下发生。实验结果的合作和比较将阐明键断裂过程,并了解C-H活化如何在这些技术体系中发生。实验将在犹他大学和法国萨克雷进行。法国小组将进行光敏C-H键活化“表面”模型实验。犹他大学的金属氧化物/甲烷实验对这些进行了补充。实验结果的合作和比较将阐明键断裂过程,并促进对这些技术体系中碳氢活化如何发生的理解。研究生将受益于高级培训和参与由国际团队进行的合作实验。该奖项代表了美国方面对NSF和CNRS的平行提案。美国国家科学基金会将支付美国研究员及其学生的旅费和生活费。法国研究中心将支持法国研究人员和学生访问美国。
项目成果
期刊论文数量(0)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
专利数量(0)
数据更新时间:{{ journalArticles.updateTime }}
{{
item.title }}
{{ item.translation_title }}
- DOI:
{{ item.doi }} - 发表时间:
{{ item.publish_year }} - 期刊:
- 影响因子:{{ item.factor }}
- 作者:
{{ item.authors }} - 通讯作者:
{{ item.author }}
数据更新时间:{{ journalArticles.updateTime }}
{{ item.title }}
- 作者:
{{ item.author }}
数据更新时间:{{ monograph.updateTime }}
{{ item.title }}
- 作者:
{{ item.author }}
数据更新时间:{{ sciAawards.updateTime }}
{{ item.title }}
- 作者:
{{ item.author }}
数据更新时间:{{ conferencePapers.updateTime }}
{{ item.title }}
- 作者:
{{ item.author }}
数据更新时间:{{ patent.updateTime }}
William Breckenridge其他文献
William Breckenridge的其他文献
{{
item.title }}
{{ item.translation_title }}
- DOI:
{{ item.doi }} - 发表时间:
{{ item.publish_year }} - 期刊:
- 影响因子:{{ item.factor }}
- 作者:
{{ item.authors }} - 通讯作者:
{{ item.author }}
{{ truncateString('William Breckenridge', 18)}}的其他基金
Full-Collision and Half-Collision Studies of the Dynamics of Model C-H Bond Activation Processes
C-H键活化过程动力学的全碰撞和半碰撞研究
- 批准号:
0093443 - 财政年份:2001
- 资助金额:
$ 1.8万 - 项目类别:
Continuing Grant
Spectroscopy of, and Dynamics Within, Atom.(Rare-Gas)n and Atom.(Molecule)n van der Waals Complexes
原子(稀有气体)n 和原子(分子)n 范德华配合物的光谱学及其内部动力学
- 批准号:
9628696 - 财政年份:1996
- 资助金额:
$ 1.8万 - 项目类别:
Standard Grant
Spectroscopy and Excited State Dynamics of Complexes of Dihydrogen and Methane with Metal Atoms
二氢和甲烷与金属原子配合物的光谱学和激发态动力学
- 批准号:
9215335 - 财政年份:1993
- 资助金额:
$ 1.8万 - 项目类别:
Continuing Grant
U.S.-France Cooperative Research: Laser Excitation of Van der Waals Complexes of Metal Atoms with H2
美法合作研究:激光激发金属原子与H2的范德华配合物
- 批准号:
9115831 - 财政年份:1992
- 资助金额:
$ 1.8万 - 项目类别:
Standard Grant
Energy Transfer and Reaction of Excited Metal Atoms and Dimers
激发金属原子和二聚体的能量转移和反应
- 批准号:
8906125 - 财政年份:1989
- 资助金额:
$ 1.8万 - 项目类别:
Continuing Grant
US-France Cooperative Research: Laser Excitation of Van derWaals Complexes of Metal Atoms.
美法合作研究:金属原子范德华配合物的激光激发。
- 批准号:
8611837 - 财政年份:1987
- 资助金额:
$ 1.8万 - 项目类别:
Standard Grant
Laser Excitation of Van der Waals Complexes of Metal Atoms: Half-Collision Versus Full-Collision Dynamics
金属原子范德华配合物的激光激发:半碰撞与全碰撞动力学
- 批准号:
8603613 - 财政年份:1986
- 资助金额:
$ 1.8万 - 项目类别:
Continuing Grant
State-To-State Chemistry and Energy Transfer Using the LaserPump-And-Probe Technique (Chemistry)
使用激光泵浦探针技术进行状态间化学和能量转移(化学)
- 批准号:
8304879 - 财政年份:1983
- 资助金额:
$ 1.8万 - 项目类别:
Continuing Grant
State-To-State Chemistry and Energy-Transfer Using the LaserPump-And-Probe Technique
使用激光泵浦探针技术进行态间化学和能量转移
- 批准号:
8007033 - 财政年份:1980
- 资助金额:
$ 1.8万 - 项目类别:
Continuing Grant
Internal-State Energy Distributions in the Products of Reactions Involving Electronically Excited Atoms
涉及电子激发原子的反应产物的内态能量分布
- 批准号:
7707603 - 财政年份:1977
- 资助金额:
$ 1.8万 - 项目类别:
Continuing Grant
相似海外基金
IRES: U.S.-France Cooperative Research in Engineering Innovative Software Systems with Applications to Maritime Transportation Logistics
IRES:美法合作研究工程创新软件系统及其应用于海上运输物流
- 批准号:
0729792 - 财政年份:2007
- 资助金额:
$ 1.8万 - 项目类别:
Standard Grant
U.S.-France Cooperative Research (INRIA): A Semantic Foundation For C++ based IC/System Design
美法合作研究 (INRIA):基于 C 的 IC/系统设计的语义基础
- 批准号:
0554678 - 财政年份:2005
- 资助金额:
$ 1.8万 - 项目类别:
Standard Grant
U.S.-France Cooperative Research: Probing Dynamics in Open Shell Atoms and Molecules using Two Photons Experiments
美法合作研究:利用两个光子实验探测开壳原子和分子的动力学
- 批准号:
0440633 - 财政年份:2005
- 资助金额:
$ 1.8万 - 项目类别:
Standard Grant
U.S.-France Cooperative Research: Modelling and Interrogation of Cancellous Bone
美法合作研究:松质骨的建模和研究
- 批准号:
0438765 - 财政年份:2005
- 资助金额:
$ 1.8万 - 项目类别:
Standard Grant
U.S.-France Cooperative Research: Energetics and Conformational Changes of SNARE-mediated Fusion
美法合作研究:SNARE介导的融合的能量学和构象变化
- 批准号:
0437230 - 财政年份:2005
- 资助金额:
$ 1.8万 - 项目类别:
Standard Grant
U.S.-France Cooperative Research: Transcriptional and Posttranscriptional Regulation of the Sodium Pump
美法合作研究:钠泵的转录和转录后调控
- 批准号:
0340622 - 财政年份:2004
- 资助金额:
$ 1.8万 - 项目类别:
Standard Grant
U.S.-France Cooperative Research: Genetics and Chemical Ecology of Reticulitermes Termites
美法合作研究:散白蚁的遗传学和化学生态学
- 批准号:
0233238 - 财政年份:2003
- 资助金额:
$ 1.8万 - 项目类别:
Standard Grant
U.S.-France Cooperative Research: Flows of Grains Down Inclined Channels
美法合作研究:谷物沿着倾斜渠道的流动
- 批准号:
0233212 - 财政年份:2003
- 资助金额:
$ 1.8万 - 项目类别:
Standard Grant
U.S.-France Cooperative Research: Passivity Based Control of Networked Control Systems
美法合作研究:网络控制系统的无源控制
- 批准号:
0128656 - 财政年份:2002
- 资助金额:
$ 1.8万 - 项目类别:
Standard Grant
U.S.-France Cooperative Research: Functional Characterization of Phage-Type RNA Polymerases in Higher Plants
美法合作研究:高等植物噬菌体型RNA聚合酶的功能表征
- 批准号:
0128903 - 财政年份:2002
- 资助金额:
$ 1.8万 - 项目类别:
Standard Grant