Spectroscopy of Molecular Complexes

分子复合物的光谱学

• 批准号: 0138521
• 负责人: William Klemperer
• 金额: $ 61.97万
• 依托单位: Harvard University
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2002
• 资助国家: 美国
• 起止时间: 2002-04-15 至 2006-03-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0138521&HistoricalAwards=false
• 关键词: Spectroscopy; Molecular; Complexes

In this project funded by the Experimental Physical Chemistry Program of the Chemistry Division, Klemperer will investigate the properties of relatively strong bound molecular complexes in their ground electronic state, but excited to high energies in the range between 10,000 and 15,000 cm-1. This work will provide quantitative data on the potential energy surfaces of hydrogen bonded molecular complexes. Studies will be performed on complexes formed with He and H2, the rotational spectroscopy of high-energy isomers will be carried out, and the spectroscopy of high overtones will be pursued.This research will develop new areas of the spectroscopy of hydrogen bonded molecular complexes. Students and postdoctoral research associates will participate in this work. They will receive training in theoretical and experimental techniques of high resolution molecular spectroscopy in preparation for advanced studies or entry into the scientific/technological workforce.

在这个由化学部实验物理化学计划资助的项目中，Klemperer将研究相对较强的结合分子复合物在基态电子状态下的性质，但激发到10，000和15，000 cm-1之间的高能量。这项工作将提供氢键分子复合物势能面的定量数据。开展He与H2形成的配合物的研究，开展高能同分异构体的转动光谱研究，开展高泛频光谱研究，开拓氢键分子配合物光谱研究的新领域。学生和博士后研究人员将参与这项工作。 他们将接受高分辨率分子光谱学理论和实验技术的培训，为高级研究或进入科学/技术劳动力做准备。