RUI: Phosphorescent cyclodextrin/bromonaphthalene complexes

RUI：磷光环糊精/溴萘配合物

• 批准号: 0240213
• 负责人: Merlyn Schuh
• 金额: $ 18.51万
• 依托单位: Davidson College
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2003
• 资助国家: 美国
• 起止时间: 2003-03-15 至 2006-02-28
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0240213&HistoricalAwards=false
• 关键词: RUI; Phosphorescent; cyclodextrin; bromonaphthalene; complexes

In this project, funded by the Experimental Physical Chemistry Program of the Chemistry Division, the PI will investigate the supramolecular dynamics of cyclodextrins (CDxs), and the factors that control the formation and stability of binary and ternary (1 guest: 2 host) molecular complexes. The complexes consist of bromonaphthalene derivatives as guests and a host, which is primarily alpha-CDx. Among other things the research will determine the binding constants and thermodynamic quantities for formation and dissociation for the 1:1 and 1:2 ground state complexes, as well as the rate constants for formation and dissociation. This research will be conducted in a college and will be performed with undergraduate students.

在该项目中，由化学部实验物理化学计划资助，PI将研究环糊精（CDxs）的超分子动力学，以及控制二元和三元（1客体：2主体）分子复合物形成和稳定性的因素。 该复合物由作为客体的溴代萘衍生物和主要为α-CDx的主体组成。 除其他外，研究将确定1：1和1：2基态复合物的形成和解离的结合常数和热力学量，以及形成和解离的速率常数。 这项研究将在一所大学进行，并将与本科生进行。