Fourier Imaging Correlation Spectroscopy in Polymers and Small Molecular Liquids

聚合物和小分子液体中的傅里叶成像相关光谱

• 批准号: 0303715
• 负责人: Andrew Marcus
• 金额: $ 45万
• 依托单位: University of Oregon Eugene
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2003
• 资助国家: 美国
• 起止时间: 2003-05-01 至 2006-04-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0303715&HistoricalAwards=false
• 关键词: Fourier; Imaging; Correlation; Spectroscopy; Polymers

In this project, funded by the Experimental Physical Chemistry Program of the Chemistry Division, Marcus will do research on Fourier Correlation Imaging Spectroscopy (FCIS) of polymers and super-cooled molecular liquids. The work consists of four tasks: 1) to improve the sensitivity of the technique to detect density fluctuations from molecular ensembles over time scales ranging from one hundred thousandths of a second to 1000 seconds; 2) to develop a polarization sensitive version of FCIS; 3) to combine FCIS with two-color and electronic energy transfer (EET) measurements; and 4) to extend the FCIS technique to study fluctuations of transition dipole relaxations on sub-nanosecond time scales. These developments will be applied to several carefully selected molecules and polymers to answer critical questions about the molecular shape, polymer backbone flexibility, intermolecular cohesive forces, and other critical problems of flexible polymers and super-cooled molecular liquids. This is an interdisciplinary project that builds bridges between physical chemistry, materials science, and biology. Graduate as well as undergraduate students will participate in the research and will acquire skills and knowledge of advanced, state-of-the-art experimental and theoretical techniques.

在该项目中，马库斯将研究聚合物和过冷分子液体的傅立叶相关成像光谱（FCIS），该项目由化学部门的实验物理化学项目资助。这项工作包括四项任务：1)提高该技术在十万分之一秒到1000秒的时间尺度上检测分子集合密度波动的灵敏度；2)开发极化敏感版FCIS；3)将FCIS与双色和电子能量转移（EET）测量相结合；4)扩展FCIS技术在亚纳秒时间尺度上研究跃迁偶极子弛豫的波动。这些发展将应用于一些精心挑选的分子和聚合物，以回答有关分子形状、聚合物主链柔韧性、分子间凝聚力以及柔性聚合物和过冷分子液体的其他关键问题。这是一个在物理化学、材料科学和生物学之间建立桥梁的跨学科项目。研究生和本科生将参与研究，并将获得先进的，最先进的实验和理论技术的技能和知识。