Investigations of homogeneously catalzyed reactions in micellar solvent systems (A02)

胶束溶剂体系中均相催化反应的研究（A02）

• 批准号: 166340742
• 金额: --
• 依托单位: Arbeitsgruppe Mehrphasenreaktionstechnik
• 依托单位国家: 德国
• 项目类别: CRC/Transregios
• 财政年份: 2010
• 资助国家: 德国
• 起止时间: 2009-12-31 至 2020-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/166340742?language=en
• 关键词: Investigations; homogeneously; catalzyed; reactions; micellar

On the basis of the results from the previous founding periods, a reaction mixture for the reductive amination of 1-undecanal will be formulated by the use of micellar solvent systems. The rational selection of an optimal phase system for an unknown reaction will be the focus of this work. A fast and efficient selection of an appropriate surfactant during the process synthesis is based on the simulta-neous optimization of reaction conditions and catalyst recycling. In addition, detailed kinetic studies will be performed to develop a macrokinetic model for the reductive amination, suitable for reactor design and process control.

在以前的研究结果的基础上，将通过使用胶束溶剂体系配制用于1-十一醛还原胺化的反应混合物。对于未知反应，合理选择最佳相系将是本工作的重点。在合成过程中快速有效地选择合适的表面活性剂是基于同时优化反应条件和催化剂循环。此外，将进行详细的动力学研究，以开发适合于反应器设计和工艺控制的还原胺化宏观动力学模型。