Organosilicon Intermediates and Related Systems: A Molecular Beam Approach

有机硅中间体和相关系统：分子束方法

• 批准号: 0445637
• 负责人: Mark Fink
• 金额: $ 43.2万
• 依托单位: Tulane University
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2005
• 资助国家: 美国
• 起止时间: 2005-05-01 至 2008-08-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0445637&HistoricalAwards=false
• 关键词: Organosilicon; Intermediates; Related; Systems; Molecular

With this new award the Organic and Macromolecular Chemistry Program supports the work of Professors Mark Fink and Mark Sulkes of the Chemistry Department at Tulane University. This research project will involve the use of molecular beams to investigate short-lived organosilicon intermediates and related energetic molecules. Intermediates to be studied include group 14 carbene analogs and doubly and triply bonded main group species. The unique thrust of this research arises from an interdisciplinary collaboration combining molecular beam spectroscopy and synthetic/mechanistic organometallic chemistry. Comprehensive use of these combined methods will provide significant new data on reactive main group species and will complement methods customarily used to study these intermediates.The broader impacts of this proposal involve the training of undergraduates and graduate students in an interdisciplinary project that crosses the boundaries between physical, inorganic, and organic chemistry. The research will prepare students for important present day interdisciplinary enterprises such as materials chemistry and environmental chemistry.

通过这一新奖项，有机和高分子化学项目支持杜兰大学化学系马克·芬克（Mark Fink）和马克·苏克斯（Mark Sulkes）教授的工作。该研究项目将涉及使用分子束来研究短寿命的有机硅中间体和相关的高能分子。 要研究的中间体包括第 14 族卡宾类似物以及双键和三键主族物质。 这项研究的独特主旨源于分子束光谱学和合成/机械有机金属化学相结合的跨学科合作。 这些组合方法的综合使用将提供有关反应性主族物种的重要新数据，并将补充通常用于研究这些中间体的方法。该提案的更广泛影响包括在跨越物理、无机和有机化学之间界限的跨学科项目中对本科生和研究生进行培训。该研究将为学生进入材料化学和环境化学等当今重要的跨学科企业做好准备。