The Analysis, Reactions and Growth of Aerosol Particles Studied by Vacuum UV Photoionization Mass Spectrometry
真空紫外光电离质谱法研究气溶胶颗粒的分析、反应和生长
基本信息
- 批准号:0509837
- 负责人:
- 金额:--
- 依托单位:
- 依托单位国家:美国
- 项目类别:Continuing Grant
- 财政年份:2005
- 资助国家:美国
- 起止时间:2005-08-01 至 2009-07-31
- 项目状态:已结题
- 来源:
- 关键词:
项目摘要
Tomas Baer of the University of North Carolina at Chapel Hill is supported by The Experimental Physical Chemistry Program and the Atmospheric Chemistry Program to employ vacuum ultraviolet (VUV) light to investigate complex mixtures of organic constituents in aerosols generated in laboratory flow tubes, reaction chambers, and in an outdoor smog chamber. VUV light in the form of synchrotron radiation, pulsed laser-generated radiation, and rare gas resonance lamps will be utilized to study both large and small particles. The reactivity of model aerosols will be examined as a function of their morphology. The reaction rates of coated particles as well as particles consisting of organics embedded in porous particles with ozone will be measured in the laboratory. A major emphasis will be on identification of organic constituents in secondary organic aerosols and species generated by gas-particle reactions. A rare gas resonance lamp will be installed to investigate its use for detecting small particles in smog chamber studies that do not lend themselves to pulsed laser ionization. As well, experiments at the Advanced Light Source will be directed at controlled nucleation studies in a laboratory reaction chamber. Many naturally occurring small particles in the environment are highly heterogeneous, containing mixtures of carbon, salts, metals, and organic molecules. When these particles are in contact with certain gases, the chemical reactions that occur will be affected by the particle properties. New experimental methods to study aerosol particles will be developed in this project. In addition, the new methods will be used to examine aerosol formation in controlled atmospheres that mimic real-world environmental systems. This research will be carried out by students and postdoctoral associates, who will be broadly trained in physical, analytical, and environmental chemistry.
北卡罗来纳大学教堂山分校的 Tomas Baer 在实验物理化学项目和大气化学项目的支持下,利用真空紫外 (VUV) 光来研究实验室流管、反应室和室外烟雾室中产生的气溶胶中有机成分的复杂混合物。 同步加速器辐射、脉冲激光产生的辐射和稀有气体共振灯形式的真空紫外光将用于研究大颗粒和小颗粒。模型气溶胶的反应性将作为其形态的函数进行检查。 涂覆颗粒以及由嵌入多孔颗粒中的有机物组成的颗粒与臭氧的反应速率将在实验室中测量。 主要重点是鉴定二次有机气溶胶中的有机成分和气体-颗粒反应产生的物质。 将安装稀有气体共振灯,以研究其在烟雾室研究中检测小颗粒的用途,这些小颗粒不适合脉冲激光电离。 此外,先进光源的实验将针对实验室反应室中的受控成核研究。 环境中许多天然存在的小颗粒是高度异质的,含有碳、盐、金属和有机分子的混合物。 当这些颗粒与某些气体接触时,发生的化学反应会受到颗粒性质的影响。 该项目将开发研究气溶胶颗粒的新实验方法。 此外,新方法将用于检查模拟真实环境系统的受控大气中气溶胶的形成。 这项研究将由学生和博士后研究员进行,他们将接受物理、分析和环境化学方面的广泛培训。
项目成果
期刊论文数量(0)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
专利数量(0)
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Tomas Baer其他文献
Kinetic energy release distributions for the dissociation of internal energy selected acetone ions
- DOI:
10.1016/0020-7381(77)80102-2 - 发表时间:
1977-09-01 - 期刊:
- 影响因子:
- 作者:
Donald M. Mintz;Tomas Baer - 通讯作者:
Tomas Baer
Observation of accurate ion dissociation thresholds in pulsed field ionization-photoelectron studies.
脉冲场电离光电子研究中精确离子解离阈值的观察。
- DOI:
- 发表时间:
2000 - 期刊:
- 影响因子:8.6
- 作者:
K. Weitzel;G. K. Jarvis;M. Malow;Tomas Baer;Yang Song;C. Ng - 通讯作者:
C. Ng
Ionic dissociation dynamics and energetics of hexamethyldigermanium, (CH<sub>3</sub>)<sub>6</sub>Ge<sub>2</sub>, by threshold photoelectron-photoion coincidence spectroscopy
- DOI:
10.1016/j.cplett.2017.06.035 - 发表时间:
2017-09-16 - 期刊:
- 影响因子:
- 作者:
Juan Z. Dávalos;Tomas Baer;Carlos Blancas - 通讯作者:
Carlos Blancas
Tomas Baer的其他文献
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{{ truncateString('Tomas Baer', 18)}}的其他基金
International Collaborative Photoionization Study of Heats of Formation and Bond Energies of Organometallic Complexes
有机金属配合物的生成热和键能的国际合作光电离研究
- 批准号:
0743000 - 财政年份:2008
- 资助金额:
-- - 项目类别:
Standard Grant
Chemistry at Ultralow Temperatures using Superfluid Helium Droplets:
使用超流氦液滴的超低温化学:
- 批准号:
0446594 - 财政年份:2005
- 资助金额:
-- - 项目类别:
Continuing Grant
U.S.-Hungary Chemistry Research: Photoionization Study of Heats of Formation and Bond Energies of Organometallic Complexes
美国-匈牙利化学研究:有机金属配合物的生成热和键能的光电离研究
- 批准号:
0434302 - 财政年份:2004
- 资助金额:
-- - 项目类别:
Standard Grant
Gas-Surface Chemistry and Analysis of Single Aerosol Particles
气体表面化学和单个气溶胶颗粒的分析
- 批准号:
0139925 - 财政年份:2002
- 资助金额:
-- - 项目类别:
Standard Grant
U.S.-Hungary: The Spectroscopy and Bond Energies of Gas Phase Organometallic Complexes
美国-匈牙利:气相有机金属配合物的光谱学和键能
- 批准号:
0000232 - 财政年份:2000
- 资助金额:
-- - 项目类别:
Standard Grant
Conformational Analysis and Energetics of Cyclic and Open Chain Ketones, Ethers, and Hydrocarbons
环状和开链酮、醚和烃的构象分析和能量学
- 批准号:
9727788 - 财政年份:1998
- 资助金额:
-- - 项目类别:
Continuing Grant
Conformational Analysis of Cyclic and Linear Ketones and Ethers, Including Analysis of Steroids
环状和线性酮和醚的构象分析,包括类固醇的分析
- 批准号:
9409144 - 财政年份:1994
- 资助金额:
-- - 项目类别:
Continuing Grant
US-France Collaborative Research: Low Energy Electron Production in the Photoionization of Molecules
美法合作研究:分子光电离中的低能电子产生
- 批准号:
9115887 - 财政年份:1992
- 资助金额:
-- - 项目类别:
Standard Grant
Photodissociation of Ion Clusters and Rydberg Spectroscopy of Heterocyclic Rings
离子簇的光解离和杂环的里德伯光谱
- 批准号:
9003797 - 财政年份:1990
- 资助金额:
-- - 项目类别:
Continuing Grant
The Structure and Dissociation Dynamics of Energy Selected Ions and Ion-Dipole Complexes
能量选择离子和离子偶极配合物的结构和离解动力学
- 批准号:
8706766 - 财政年份:1987
- 资助金额:
-- - 项目类别:
Continuing Grant
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Fundamentals of thin film growth from the vapor phase and through solid-state reactions
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- 批准号:
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Suppression of dendrite growth in electrochemical reactions based on modeling of growing interfaces
基于生长界面建模抑制电化学反应中的枝晶生长
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Insect growth-blocking peptide (GBP) signaling pathway mediates acute immune reactions during infectious and non-infectious stress
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