Highly Efficient and Versatile Synthesis of Polymeric Materials using Click Chemistry

利用点击化学高效、多功能地合成聚合物材料

• 批准号: 0514031
• 负责人: Craig Hawker
• 金额: $ 42万
• 依托单位: University of California-Santa Barbara
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2005
• 资助国家: 美国
• 起止时间: 2005-08-01 至 2009-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0514031&HistoricalAwards=false
• 关键词: Highly; Efficient; Versatile; Synthesis; Polymeric

The Organic and Macromolecular Chemistry Program supports Professor Craig J. Hawker at the University of California- Santa Barbara who proposes to thoroughly investigate the development of Click chemistry for the synthesis of novel polymeric materials. This work will advance click chemistry from a few select reactions to a broadly integrated concept in chemistry. The relative simplicity of click chemistry (very high yields, no protection/deprotection reactions) will allow the synthesis of new polymeric materials. Additionally, the author has chosen appropriate collaborators to carry out aspects of the research outside his expertise.The Organic and Macromolecular Chemistry Program supports Professor Craig J. Hawker who will develop non-toxic catalysts for click reactions that will be environmentally friendly and extend click chemistry to a variety of applications. The efficiency and quantitative yields of click chemistry will be an appealing option to industry and academia. The proposed research will promote learning through interesting collaborations and a creative research plan. Graduate students will greatly benefit from spending 2-3 months at the laboratory of one of the collaborators. The Science Mentoring Program will help mentor high school chemistry students who are underrepresented minorities and will also benefit the graduate students involved.

有机和高分子化学计划支持加州-圣巴巴拉大学的克雷格·J·霍克教授，他建议彻底研究用于合成新型聚合物材料的点击化学的发展。这项工作将推动点击化学从几个选择反应到一个广泛集成的化学概念。点击化学的相对简单性（非常高的产率，没有保护/脱保护反应）将允许合成新的聚合物材料。此外，作者还选择了合适的合作者来进行他专业知识之外的研究。有机和大分子化学项目支持克雷格J.霍克教授，他将开发无毒的点击反应催化剂，这将是环境友好的，并将点击化学扩展到各种应用。点击化学的效率和定量产量将是工业界和学术界的一个有吸引力的选择。拟议的研究将通过有趣的合作和创造性的研究计划促进学习。研究生将在其中一个合作者的实验室度过2-3个月，从中受益匪浅。科学指导计划将帮助指导高中化学学生谁是代表性不足的少数民族，也将有利于研究生参与。