Dynamics and Interactions in Ionic Liquids

离子液体的动力学和相互作用

基本信息

  • 批准号:
    0718391
  • 负责人:
  • 金额:
    $ 42.5万
  • 依托单位:
  • 依托单位国家:
    美国
  • 项目类别:
    Continuing Grant
  • 财政年份:
    2007
  • 资助国家:
    美国
  • 起止时间:
    2007-08-15 至 2011-07-31
  • 项目状态:
    已结题

项目摘要

The Experimental Physical Chemistry program of the Division of Chemistry supports the research of Professor Edward Castner of the Department of Chemistry and Chemical Biology at Rutgers, The State University of New Jersey. Castner and his research group will study the physical and chemical properties of new classes of ionic liquids. Time-resolved optical spectroscopy and nuclear magnetic resonance spectroscopy will be used to study the dynamics, interactions, and transport in ionic liquids as a function of temperature. The research will include the detailed evaluation of the impact of silicon substitutions in alkyl side chains on the properties of these materials and the comparison of intermolecular interactions in ionic liquids with those of isoelectronic, neutral homologs. NMR diffusion studies of ionic liquids with varying concentrations of water will be used to model transport relevant to ionic liquids in fuel cells. The overall goal of the work is to study carefully selected ionic liquids and model systems in sufficient detail to lead to better a priori predictions of their properties. The research should provide a better understanding of the liquid properties of ionic liquids, especially their viscosities and conductivities. Ionic liquids are an important new class of chemical solvents comprised of molten salts that have many special properties. The unique electrical characteristics of these liquids should lead to their use in improved batteries, fuel cells and solar photocells. The Castner group will collaborate with a diverse range of researchers, including students, postdoctoral fellows, faculty, and scientific staff at Brookhaven National Laboratory, William Paterson University, and the City University of New York (Hunter College and Brooklyn College). The project will train undergraduates, graduate students, and post-doctoral researchers in modern techniques in experimental and theoretical physical chemistry.
化学系的实验物理化学项目支持新泽西州立大学罗格斯大学化学和化学生物学系爱德华·卡斯特纳教授的研究。卡斯特纳和他的研究小组将研究新型离子液体的物理和化学性质。时间分辨光学光谱和核磁共振光谱将被用来研究离子液体中的动力学、相互作用和输运随温度的变化。这项研究将包括详细评估烷基侧链上的硅取代对这些材料性能的影响,以及离子液体中分子间相互作用与等电子、中性同系物的比较。具有不同水浓度的离子液体的核磁共振扩散研究将被用来模拟与燃料电池中的离子液体相关的传输。这项工作的总体目标是对精心挑选的离子液体和模型体系进行足够详细的研究,以更好地对其性质进行先验预测。这项研究应该能更好地了解离子液体的液体性质,特别是它们的粘度和导电性。离子液体是一类重要的新型化学溶剂,由熔融盐类组成,具有许多特殊性质。这些液体独特的电学特性应该会导致它们在改进的电池、燃料电池和太阳能光电池中使用。卡斯特纳团队将与各种各样的研究人员合作,包括布鲁克海文国家实验室、威廉·帕特森大学和纽约城市大学(亨特学院和布鲁克林学院)的学生、博士后研究员、教职员工和科研人员。该项目将对本科生、研究生和博士后研究人员进行实验和理论物理化学方面的现代技术培训。

项目成果

期刊论文数量(0)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
专利数量(0)

数据更新时间:{{ journalArticles.updateTime }}

{{ item.title }}
{{ item.translation_title }}
  • DOI:
    {{ item.doi }}
  • 发表时间:
    {{ item.publish_year }}
  • 期刊:
  • 影响因子:
    {{ item.factor }}
  • 作者:
    {{ item.authors }}
  • 通讯作者:
    {{ item.author }}

数据更新时间:{{ journalArticles.updateTime }}

{{ item.title }}
  • 作者:
    {{ item.author }}

数据更新时间:{{ monograph.updateTime }}

{{ item.title }}
  • 作者:
    {{ item.author }}

数据更新时间:{{ sciAawards.updateTime }}

{{ item.title }}
  • 作者:
    {{ item.author }}

数据更新时间:{{ conferencePapers.updateTime }}

{{ item.title }}
  • 作者:
    {{ item.author }}

数据更新时间:{{ patent.updateTime }}

Edward Castner其他文献

Edward Castner的其他文献

{{ item.title }}
{{ item.translation_title }}
  • DOI:
    {{ item.doi }}
  • 发表时间:
    {{ item.publish_year }}
  • 期刊:
  • 影响因子:
    {{ item.factor }}
  • 作者:
    {{ item.authors }}
  • 通讯作者:
    {{ item.author }}

{{ truncateString('Edward Castner', 18)}}的其他基金

Collaborative Research: Ionic Liquids at Interfaces: from Bulk Structure to Tunable Films
合作研究:界面离子液体:从块体结构到可调谐薄膜
  • 批准号:
    1664809
  • 财政年份:
    2017
  • 资助金额:
    $ 42.5万
  • 项目类别:
    Continuing Grant
Collaborative Research: Ionic Liquid Structural Paradigms- Beyond Alkyl Tails
合作研究:离子液体结构范式——超越烷基尾
  • 批准号:
    1362272
  • 财政年份:
    2014
  • 资助金额:
    $ 42.5万
  • 项目类别:
    Standard Grant
Collaborative Research: Ionic Liquids- Cations in the Spotlight and Single Atom Changes with Large Consequences
合作研究:离子液体——聚光灯下的阳离子和具有重大后果的单原子变化
  • 批准号:
    1112077
  • 财政年份:
    2011
  • 资助金额:
    $ 42.5万
  • 项目类别:
    Continuing Grant
Dynamics, Microviscosity, and Length Scales in Aqueous Polymer Solutions
聚合物水溶液中的动力学、微粘度和长度尺度
  • 批准号:
    0239390
  • 财政年份:
    2003
  • 资助金额:
    $ 42.5万
  • 项目类别:
    Standard Grant
"ULTRAFAST MOLECULAR DYNAMICS: SUPERCRITICAL FLUIDS, AND INTERFACIAL WATER ON BIOMOLECULES"
“超快分子动力学:超临界流体和生物分子上的界面水”
  • 批准号:
    9903663
  • 财政年份:
    1999
  • 资助金额:
    $ 42.5万
  • 项目类别:
    Fellowship Award
Ultrafast Dynamics and Spectroscopy of Photosystem I Subunits at Low Temperatures
低温下光系统 I 亚基的超快动力学和光谱学
  • 批准号:
    8702541
  • 财政年份:
    1987
  • 资助金额:
    $ 42.5万
  • 项目类别:
    Standard Grant
NATO Postdoctoral Fellow
北约博士后研究员
  • 批准号:
    8751126
  • 财政年份:
    1987
  • 资助金额:
    $ 42.5万
  • 项目类别:
    Fellowship Award

相似海外基金

CAREER: Elucidating the Mechanism of Ionic Liquid-Coated Nanoparticle Interactions with Blood Components
职业:阐明离子液体涂层纳米粒子与血液成分相互作用的机制
  • 批准号:
    2236629
  • 财政年份:
    2023
  • 资助金额:
    $ 42.5万
  • 项目类别:
    Continuing Grant
Influence of Structure, Interionic Interactions, Interfacial slip and Viscous-electric Coupling Phenomena on the Rheology of Nanoconfined Ionic Liquids
结构、离子间相互作用、界面滑移和粘电耦合现象对纳米限域离子液体流变性的影响
  • 批准号:
    1916609
  • 财政年份:
    2019
  • 资助金额:
    $ 42.5万
  • 项目类别:
    Standard Grant
RII Track-4: Elucidating Enzyme-Ionic Liquid Interactions to Enable Effective Lignin Valorization
RII Track-4:阐明酶-离子液体相互作用以实现有效的木质素增值
  • 批准号:
    1929122
  • 财政年份:
    2019
  • 资助金额:
    $ 42.5万
  • 项目类别:
    Standard Grant
Self-healing soft materials based on supramolecular interactions in ionic liquids
基于离子液体中超分子相互作用的自修复软材料
  • 批准号:
    18K14280
  • 财政年份:
    2018
  • 资助金额:
    $ 42.5万
  • 项目类别:
    Grant-in-Aid for Early-Career Scientists
Cellulose derivatization for analysis of interactions between cellulose and ionic liquids
纤维素衍生化用于分析纤维素和离子液体之间的相互作用
  • 批准号:
    16K18731
  • 财政年份:
    2016
  • 资助金额:
    $ 42.5万
  • 项目类别:
    Grant-in-Aid for Young Scientists (B)
Accurate and Efficient Modeling of Biomolecular Ionic Interactions: Charge Redistribution, Polarization and Dispersion
生物分子离子相互作用的准确有效的建模:电荷重新分布、极化和色散
  • 批准号:
    9083227
  • 财政年份:
    2016
  • 资助金额:
    $ 42.5万
  • 项目类别:
Ionic competition in protein-nucleic acid interactions
蛋白质-核酸相互作用中的离子竞争
  • 批准号:
    1608866
  • 财政年份:
    2016
  • 资助金额:
    $ 42.5万
  • 项目类别:
    Standard Grant
Cooperative Motion of Microswimmers: The Influence of Ionic and Reactive Screening on Hydrodynamic Interactions in Complex Fluids
微型游泳者的协作运动:离子和反应筛选对复杂流体中水动力相互作用的影响
  • 批准号:
    254456455
  • 财政年份:
    2014
  • 资助金额:
    $ 42.5万
  • 项目类别:
    Priority Programmes
Elucidating Water-Ionic Liquid-Enzyme Mixtures Interactions for Enhanced Deconstruction of Cellulosic Biomass
阐明水-离子液体-酶混合物的相互作用以增强纤维素生物质的解构
  • 批准号:
    1337044
  • 财政年份:
    2013
  • 资助金额:
    $ 42.5万
  • 项目类别:
    Standard Grant
RUI: Spectroscopic studies of halogen substitution effects on covalent and noncovalent interactions in ionic and neutral species
RUI:卤素取代对离子和中性物质中共价和非共价相互作用的光谱研究
  • 批准号:
    1214070
  • 财政年份:
    2012
  • 资助金额:
    $ 42.5万
  • 项目类别:
    Continuing Grant
{{ showInfoDetail.title }}

作者:{{ showInfoDetail.author }}

知道了