Di- to tetranuclear compounds incorporating highly anisotropic paramagnetic metal ions (A03)

含有高度各向异性顺磁金属离子的二核至四核化合物 (A03)

• 批准号: 189428190
• 金额: --
• 依托单位: Institut für Anorganische Chemie (aoc)
• 依托单位国家: 德国
• 项目类别: CRC/Transregios
• 财政年份: 2011
• 资助国家: 德国
• 起止时间: 2010-12-31 至 2021-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/189428190?language=en
• 关键词: Di; tetranuclear; compounds; incorporating; highly

This 3MET project provides heterometallic 3MET complexes of three paramagnetic metal ions, ideally from three different areas of the Periodic Table. The three ions should interact cooperatively to produce exotic electronic and magnetic signatures not expected of the single ion systems: this represents targeting the ultimate “3MET compound” which the project has been building towards. This major goal will be pursued from the beginning of FP3 in order to ensure a successful outcome. The project addresses the challenge of structural characterization, of the exploration, and of the explanation of the electronic and magnetic behavior of these complexes

这个3MET项目提供了三个顺磁性金属离子的异金属3MET络合物，理想情况下来自元素周期表的三个不同区域。这三个离子应该相互作用，以产生单离子系统所没有的奇异的电子和磁学特征：这代表着以该项目一直致力于的最终“3MET化合物”为目标。这一主要目标将从第三次缔约方会议开始就开始实现，以确保取得成功的结果。该项目解决了结构表征、探索和解释这些络合物的电子和磁性行为的挑战。