Luminescence properties of isolated lanthanide and transition metal complexes (C07)

孤立的镧系元素和过渡金属配合物（C07）的发光特性

• 批准号: 189488016
• 金额: --
• 依托单位: Institut für Nanotechnologie (INT)
• 依托单位国家: 德国
• 项目类别: CRC/Transregios
• 财政年份: 2011
• 资助国家: 德国
• 起止时间: 2010-12-31 至 2021-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/189488016?language=en
• 关键词: Luminescence; properties; isolated; lanthanide; transition

This 3MET project investigates metal-metal interactions and functional cooperativity in photoluminescent heteronuclear lanthanide and transition metal complexes. It studies structure and coordination of the metal centers. It screens these complexes for visible to near infrared down conversion and for near infrared to visible up conversion, both of which are highly cooperative in nature. It correlates structure and luminescence, and it investigates the influence of environmental interactions on non-radiative transitions. It com-bines gas phase luminescence studies on mass-selected ions, measurements in solution and on crystals, and quantum-chemical calculations.

这个3 MET项目研究光致发光的镧系和过渡金属配合物中的金属-金属相互作用和功能协同性。它研究金属中心的结构和配位。它筛选这些复合物的可见光到近红外的下转换和近红外到可见光的上转换，这两者在性质上都是高度合作的。它将结构和发光联系起来，并研究环境相互作用对非辐射跃迁的影响。它结合了气相发光研究的质量选择离子，测量溶液和晶体，和量子化学计算。