SusChEM: RUI: Accessing Reactive, Unsaturated Co(I) Fragments for Stoichiometric and Catalytic C-H Bond Activation/Functionalization

SusChEM:RUI:获取反应性不饱和 Co(I) 片段以进行化学计量和催化 C-H 键活化/功能化

基本信息

  • 批准号:
    1300508
  • 负责人:
  • 金额:
    $ 14.62万
  • 依托单位:
  • 依托单位国家:
    美国
  • 项目类别:
    Standard Grant
  • 财政年份:
    2013
  • 资助国家:
    美国
  • 起止时间:
    2013-07-01 至 2016-10-31
  • 项目状态:
    已结题

项目摘要

Support from the Chemical Catalysis Program of the Chemistry Division of the National Science Foundation will allow Professor Christopher Bradley of Mount St. Mary's University to investigate the ability of cyclopentadienyl (Cp) cobalt(I) sources to mediate stoichiometric and catalytic carbon-hydrogen bond activation. A combination of computational and synthetic studies will permit structure/reactivity trends to be established for C-H activation in both monomeric and aggregate [Cp-Co] fragments. Specifically, catalytic alkane dehydrogenation will be targeted. The proposed research involves continued mentoring of both high school and undergraduate students in a research environment. In particular, economically disadvantaged high school students in the Maryland and Washington D.C. metro area will have the opportunity to conduct summer research in synthetic chemistry. The students will be encouraged to continue their college education at Mount St. Mary's, through the Third Century Scholar Program.The conversion of aliphatic hydrocarbons to unsaturated products has great value to a range of fields, including commodity chemical and polymer synthesis. Performing this transformation using more abundant metals as catalysts under milder conditions would therefore be ideal. The abilities developed by both high school and undergraduate students supported by this award will prepare them well for pursuit of advanced degrees in the chemical sciences.
来自国家科学基金会化学部化学催化计划的支持将使圣玛丽山大学的克里斯托弗布拉德利教授能够研究三价(Cp)钴(I)源介导化学计量和催化碳-氢键活化的能力。计算和合成研究的结合将允许在单体和聚集体[Cp-Co]片段中建立C-H活化的结构/反应性趋势。具体而言,将以催化烷烃脱氢为目标。拟议的研究涉及在研究环境中继续指导高中和本科生。特别是,在马里兰州和华盛顿特区的经济困难的高中学生将有机会进行合成化学的夏季研究。通过第三个世纪学者计划,将鼓励学生们继续在圣玛丽玛丽接受大学教育。脂肪烃转化为不饱和产物对包括商品化学品和聚合物合成在内的一系列领域具有重要价值。因此,使用更丰富的金属作为催化剂在温和的条件下进行这种转化是理想的。该奖项支持的高中生和本科生所培养的能力将为他们攻读化学科学高级学位做好准备。

项目成果

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Christopher Bradley其他文献

PO-05-054 UNVEILING THE ROLE OF RIGHT ATRIUM STRUCTURES IN ATRIAL FIBRILLATION RECURRENCE: INSIGHTS FROM STRUCTURAL ANALYSIS AND COMPUTATIONAL MODELING
PO-05-054 揭示右心房结构在心房颤动复发中的作用:来自结构分析和计算建模的见解
  • DOI:
    10.1016/j.hrthm.2025.03.1452
  • 发表时间:
    2025-04-01
  • 期刊:
  • 影响因子:
    5.700
  • 作者:
    Roshan Sharma;Martin K. Stiles;Anuradha Kulathilaka;James Kennelly;Gregory B. Sands;Christopher Bradley;Mark L. Trew;Vadim V. Fedorov;Jichao Zhao
  • 通讯作者:
    Jichao Zhao
Transendothelial migration of lymphocytes in chronic lymphocytic leukaemia is impaired and involved down‐regulation of both L‐selectin and CD23
慢性淋巴细胞白血病中淋巴细胞的跨内皮迁移受损并涉及 L-选择素和 CD23 的下调
  • DOI:
    10.1111/j.1365-2141.1999.01278.x
  • 发表时间:
    1999
  • 期刊:
  • 影响因子:
    6.5
  • 作者:
    Joan R. Chen;B. Gu;L. Dao;Christopher Bradley;S. Mulligan;James S. Wiley
  • 通讯作者:
    James S. Wiley
FOR PATIENTS WITH SEVERE LOWER GI BLEEDING (LGIB), URGENT COLON CAPSULE ENDOSCOPY HAS A SIGNIFICANTLY HIGHER DIAGNOSTIC YIELD THAN CTA OR RBC SCANNING
  • DOI:
    10.1016/j.gie.2024.04.2918
  • 发表时间:
    2024-06-01
  • 期刊:
  • 影响因子:
  • 作者:
    Dennis Jensen;Rome Jutabha;Peerapol Wangrattanapranee;Denis Nguyen;Stephen Kim;Sonia Sharma;Christopher Bradley
  • 通讯作者:
    Christopher Bradley
Learning and Planning for Temporally Extended Tasks in Unknown Environments
未知环境中临时扩展任务的学习和规划
An integrative multiscale view of early cardiac looping.
早期心脏循环的综合多尺度视图。
  • DOI:
  • 发表时间:
    2021
  • 期刊:
  • 影响因子:
    3.1
  • 作者:
    Nazanin Ebrahimi;Christopher Bradley;P. Hunter
  • 通讯作者:
    P. Hunter

Christopher Bradley的其他文献

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{{ truncateString('Christopher Bradley', 18)}}的其他基金

MRI Consortium: Acquisition of a Single Crystal X-Ray Diffractometer for Research and Pedagogy at Primarily Undergraduate Institutions
MRI 联盟:采购一台单晶 X 射线衍射仪,用于主要本科机构的研究和教学
  • 批准号:
    1337428
  • 财政年份:
    2013
  • 资助金额:
    $ 14.62万
  • 项目类别:
    Standard Grant

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