Novel Characterization of Porous Structure and Surface Chemistry of Carbon

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The aim of this project is to develop novel characterisation methods that probe the structure and surface chemistry of carbons, ranging from highly graphitised thermal carbon black through ordered mesoporous carbon to disordered porous activated carbon. The project plans to develop a new generic molecular model based on wedge-shaped pores. Conventional parallel sided pore models fail to account for real structures and therefore for the physics of adsorption in real materials. The project then plans to back the theoretical model with high-resolution experimental measurements. It is expected that the model will unify the structural analysis for all carbons and account for all experimental isotherms within a rational and physically plausible framework.