Collaborative Research: Kinetics and Mechanism of Restructuring of Atmospheric Soot and Associated Impact on Light Absorption

纳米颗粒大气中的烟尘颗粒在形状、大小和化学成分上都很复杂。它们可以不同地被观察为由元素碳(石墨烯或石墨烯结构中的EC-)或有机碳化合物(具有氧化或其他连接的杂原子部分的有机碳氢化合物)组成的分形聚集体。其他气溶胶材料可能在内部或外部混合状态下嵌入或包裹在周围大气中老化的烟尘颗粒。我们对烟尘混合状态、烟尘形态和烟尘光学性质之间关系的有限了解，仍然是评估含碳气溶胶对直接辐射气候强迫的光学和辐射贡献的主要不确定性来源。研究人员将进行一系列实验室和计算相结合的研究，以更好地表征不同混合状态的烟尘颗粒的形成，并调查与颗粒初始状态和气溶胶老化有关的相关结构和光学性质。煤烟聚集体的混合状态和形态将通过质量迁移率测量和环境扫描电子显微镜成像相结合来确定。受实验测量的混合态和形貌约束的光学计算将提供一个直接确定的光吸收和散射范围的碳质烟尘的闭合。这项工作的一个更广泛的影响将是促进授予博士学位的教师和主要是本科教学大学的教师之间的合作。

Nanoparticulate atmospheric soot particles are complex in their shape, size and chemical composition. They can be variably observed as fractal aggregates composed of elemental carbon (EC- in graphitic or graphene structures), or organic carbon compounds (OC - hydrocarbons with oxidized or other attached heteroatom moieties). Other aerosol materials potentially embed or enmesh, in either internal or external mixing states, such soot particles as they age in the ambient atmosphere. Our limited knowledge of relationships between soot mixing state, soot morphology, and soot optical properties, remains a major source of uncertainty in evaluating the optical and radiative contribution of carbonaceous aerosols to direct radiative) climate forcing. Researchers will undertake a series of combined laboratory and computational studies to better characterize the formation of soot particles with different mixing states, and to investigate associated structural and optical properties in relation to the particle initial state and aerosol aging. Mixing states and morphology of soot aggregates will be determined from a combination of mass-mobility measurements and environmental scanning electron microscopy imaging. Optical calculations constrained by the experimentally measured mixing states and morphologies will provide a closure with directly determined light absorption and scattering by this range of carbonaceous soot.One broader impact of this work will be the promotion of collaboration between faculty at a PhD-granting and a primarily undergraduate teaching university.