Collaborative Research: U.S. GEOTRACES Pacific Meridional Transect: Thorium-232, Thorium-231 and Protactinium-231 as tracers of trace element supply and removal

合作研究：美国 GEOTRACES 太平洋经线横断面：Thorium-232、Thorium-231 和 Protactinium-231 作为微量元素供应和去除的示踪剂

• 批准号: 1737023
• 负责人: Christopher Hayes
• 金额: $ 24.98万
• 依托单位: University of Southern Mississippi
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2017
• 资助国家: 美国
• 起止时间: 2017-11-01 至 2022-10-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1737023&HistoricalAwards=false
• 关键词: Collaborative; Research; U.S.; GEOTRACES; Pacific

The goal of the international GEOTRACES program is to understand the distributions of trace chemical elements and their isotopes in the oceans. Many trace elements are essential for life and their extremely low concentrations in seawater are thought to limit biological productivity (fertility) throughout much of the ocean. This limitation, in turn, partially constrains the level of fisheries that can be supported by marine ecosystems as well as the ocean's capacity to absorb carbon dioxide from the atmosphere. Whereas the importance of these trace-element micronutrients is well established, many basic features of their ocean distribution remain unknown. Measurements of other elements and isotopes can be used to understand the processes that influence the distributions of the micronutrient elements. Two naturally-occurring radioactive isotopes that are particularly important in this regard are thorium-230 and protactinium-231, which have been designated as key parameters to be measured as part of GEOTRACES. This project will focus on the measurement of these two isotopes in order to provide critical information about the processes that supply iron to the Pacific Ocean, as well as the rates of those processes. The project will support an early career investigator, a postdoctoral researcher, and students at the undergraduate and graduate levels.Samples of seawater and of suspended particulate material will be collected along a north-south transect between Alaska and Tahiti to examine the processes that supply and remove trace elements. These samples will be analyzed for naturally-occurring radionuclides thorium-232, thorium-230 and protactinium-231. Aerosol samples and sediments collected along the transect will be analyzed as well. In collaboration with other investigators involved in the expedition, this project will:1) Interpret the distributions of thorium-232 and thorium-230 to quantify the supply of iron and other trace elements delivered by dust as well as the trace elements supplied by chemical reactions in volcanic sediments along the Alaskan margin, 2) Determine the sinking flux of major particulate phases and of particulate trace elements throughout the water column to quantify their rate of removal from the ocean, and 3) Compare the rate of trace element removal among contrasting environmental regimes to be encountered along the Alaska to Tahiti transect to identify the key physical, chemical and biological factors, such as dust supply and biological productivity, that regulate the rate of trace element removal from the ocean.

国际GEOTRACES计划的目标是了解微量化学元素及其同位素在海洋中的分布。许多微量元素是生命所必需的，它们在海水中的极低浓度被认为限制了整个海洋的生物生产力（繁殖力）。这种限制反过来又部分限制了海洋生态系统所能支持的渔业水平以及海洋从大气中吸收二氧化碳的能力。虽然这些微量元素微量营养素的重要性已得到公认，但其海洋分布的许多基本特征仍然未知。其他元素和同位素的测量可用于了解影响微量营养元素分布的过程。在这方面特别重要的两种天然存在的放射性同位素是钍-230和钚-231，它们被指定为GEOTRACES测量的关键参数。该项目将侧重于测量这两种同位素，以便提供有关向太平洋供应铁的过程以及这些过程的速率的重要信息。该项目将支助一名早期职业调查员、一名博士后研究员以及本科生和研究生，将沿阿拉斯加和塔希提岛之间的一条南北向断面沿着收集海水和悬浮颗粒物样品，以研究提供和去除微量元素的过程。将对这些样品进行天然放射性核素钍-232、钍-230和钚-231的分析。还将分析沿样带沿着收集的气溶胶样品和沉积物。在与参与考察的其他调查人员的合作下，该项目将：1）解释钍-232和钍-230的分布，以量化由灰尘提供的铁和其他微量元素的供应，以及由沿着阿拉斯加边缘的火山沉积物中的化学反应提供的微量元素，2）确定整个水柱中主要颗粒相和颗粒微量元素的下沉通量，以量化它们从海洋中的去除率，以及3）比较沿沿着阿拉斯加到塔希提岛的断面将遇到的对比环境状况之间的微量元素去除率，以确定关键的物理，化学和生物因素，如灰尘供应和生物生产力，调节微量元素从海洋中去除的速度。

项目成果

Toward Constraining Sources of Lithogenic Metals in the Northern Gulf of Mexico

限制墨西哥湾北部的岩成金属来源

• DOI: 10.1029/2022jc018523
• 发表时间: 2022
• 期刊: Journal of Geophysical Research: Oceans
• 作者: Hayes, Christopher T.;Shiller, Alan M.;Milroy, Scott P.
• 通讯作者: Milroy, Scott P.

A Lagrangian View of Trace Elements and Isotopes in the North Pacific

北太平洋微量元素和同位素的拉格朗日观

• DOI: 10.1029/2019jc015862
• 发表时间: 2020
• 期刊: Journal of Geophysical Research: Oceans
• 作者: Hayes, Christopher T.;Fitzsimmons, Jessica N.;Jensen, Laramie T.;Lanning, Nathan T.;Hatta, Mariko;McGee, David;Boyle, Edward A.
• 通讯作者: Boyle, Edward A.

The Dual Isotopic Composition of Nitrate in the Gulf of Mexico and Florida Straits

• DOI: 10.1029/2020jc016047
• 发表时间: 2020-09-01
• 期刊: JOURNAL OF GEOPHYSICAL RESEARCH-OCEANS
• 影响因子: 3.6
• 作者: Howe, Samantha;Miranda, Carlos;Knapp, Angela N.
• 通讯作者: Knapp, Angela N.

Global Ocean Sediment Composition and Burial Flux in the Deep Sea

• DOI: 10.1029/2020gb006769
• 发表时间: 2021-04-01
• 期刊: GLOBAL BIOGEOCHEMICAL CYCLES
• 影响因子: 5.2
• 作者: Hayes, Christopher T.;Costa, Kassandra M.;Zhang, Jing
• 通讯作者: Zhang, Jing