Porous compartmentalized multi-catalytic electrospun membranes for reaction cascades in one-pot using ‘Wolf-Lamb’ catalysts (A12)

使用“Wolf-Lamba”催化剂进行一锅级联反应的多孔隔室多催化电纺膜 (A12)

• 批准号: 240212256
• 金额: --
• 依托单位: Physikalisches Institut
• 依托单位国家: 德国
• 项目类别: Collaborative Research Centres
• 财政年份: 2013
• 资助国家: 德国
• 起止时间: 2012-12-31 至 2020-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/240212256?language=en
• 关键词: Porous; compartmentalized; multi; catalytic; electrospun

Compartmentalized fibrous membranes and fiber morphologies with very high porosity and diverse pore size will be explored as novel multi-catalysts carrier for site-isolated immobilisation of incompatible (Wolf-Lamb type) catalysts in one-pot cascade reactions. The side-by-side and coaxial structures established in the first part of the project offer a unique opportunity for immobilisation of multiple catalysts in a site-specific manner with additional advantages of high porosity required for mass transport, upscalability and reusability. The study will combine experiments and computer simulations to make quantitative predictions and to understand the catalytic processes in flows through geometrically complex media.

将探索具有高孔隙率和不同孔径的区隔纤维膜和纤维形态作为一锅级联反应中不相容（Wolf-Lamb型）催化剂的位点隔离固定化的新型多催化剂载体。在项目的第一部分中建立的并排和同轴结构为以特定地点的方式固定多种催化剂提供了独特的机会，并具有高孔隙率、高可扩展性和可重用性所需的额外优势。该研究将结合实验和计算机模拟来进行定量预测，并了解在几何复杂的介质中流动的催化过程。