Collaborative Research: Tracking Novel Metal Isotope Signatures during Subduction Metamorphism

合作研究：追踪俯冲变质作用过程中的新金属同位素特征

• 批准号: 1949665
• 负责人: Richard Gaschnig
• 金额: $ 22.26万
• 依托单位: University of Massachusetts Lowell
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2020
• 资助国家: 美国
• 起止时间: 2020-04-01 至 2023-12-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1949665&HistoricalAwards=false
• 关键词: Collaborative; Research; Tracking; Novel; Metal

Subduction is a key geologic process governing the Earth’s chemical evolution. Through this process, sediments bearing the chemical signatures of low-temperature interaction with the hydrosphere and atmosphere are delivered, along with ocean crust altered by interaction with seawater, to the Earth’s deep interior. With increasing depth and pressure, metamorphic changes to the subducting slab’s mineralogy lead to the release of fluids and, in some cases, melts, enriched in some elements over others. These materials may return to the Earth’s surface via the route of arc volcanism, leaving behind a chemically altered slab that continues to sink deeper into the mantle. The research broadly aims to better understand the chemical exchange that occurs between the slab and overlying mantle during subduction metamorphism using the molybdenum (Mo) and thallium (Tl) isotope tracer systems. Isotopes of Mo and Tl experience strong fractionation in the oceans, leading to distinct isotope signatures in sediments and altered ocean crust that are ultimately transferred to subduction zones. While recent research on the Mo and Tl isotope systems in volcanic arc rocks indicate that Tl isotopes match subduction zone inputs well, there is a large mismatch between the Mo isotope composition of most arcs and subduction zone inputs. The work will focus on the origins of the divergent behaviors of the Mo and Tl isotope systems and provide new understanding of the deep Earth cycling of these elements. The work uses two well-characterized suites of high pressure-low temperature (HPLT) metamorphic rocks as analogs for the chemical processes and mineralogical changes that occur in sedimentary rocks during subduction. The Schistes Lustres and related rocks from the western Alps exhibit a metamorphic gradient that ultimately reaches pressures approaching 3 GPa, but prior work has shown only limited mobile-element loss. The Catalina Schist from California represents warmer subduction metamorphic conditions and shows considerable mobile element loss. The bulk-rock Mo and Tl isotope compositions of the two sample suites will be determined in order to ascertain whether these isotope systems experience fractionation during HPLT metamorphism. In situ analysis via LA-ICP-MS will determine which minerals host these elements and how they are redistributed during progressive metamorphism. Isotope analysis of purified mineral splits will determine whether isotopic fractionation occurs between mineral phases.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

俯冲作用是控制地球化学演化的一个关键地质过程。 通过这一过程，带有与水圈和大气层低温相互作用的化学特征的沉积物，连同因与海水相互作用而改变的海洋地壳，沿着被运送到地球内部深处。 随着深度和压力的增加，俯冲板块矿物学的变质变化导致流体的释放，在某些情况下，熔融物，富集某些元素。 这些物质可能会通过弧火山作用的途径返回地球表面，留下一个化学变化的板块，继续沉入地幔更深处。 这项研究的主要目的是利用钼（Mo）和铊（Tl）同位素示踪系统更好地了解俯冲变质作用期间板片和上覆地幔之间发生的化学交换。 Mo和Tl的同位素在海洋中经历强烈的分馏，导致沉积物和最终转移到俯冲带的蚀变洋壳中的不同同位素特征。 虽然最近对火山弧岩中Mo和Tl同位素体系的研究表明Tl同位素与俯冲带输入匹配良好，但大多数弧的Mo同位素组成与俯冲带输入之间存在很大的不匹配。 这项工作将集中在钼和铊同位素系统的分歧行为的起源，并提供这些元素的地球深部循环的新认识。 这项工作使用了两套特征良好的高压低温（HPLT）变质岩作为俯冲过程中沉积岩中发生的化学过程和矿物学变化的类似物。 阿尔卑斯山西部的Lustres和相关岩石表现出变质梯度，最终达到接近3 GPa的压力，但先前的工作只显示了有限的移动元素损失。 来自加州的卡塔利纳片岩代表了较温暖的俯冲变质条件，并显示出相当大的移动的元素损失。 将确定两个样品组的岩石钼和铊同位素组成，以确定这些同位素系统是否经历分馏在HPLT变质作用。 通过LA-ICP-MS的原位分析将确定哪些矿物含有这些元素以及它们在渐进变质作用期间如何重新分布。 纯化矿物分裂的同位素分析将确定矿物相之间是否发生同位素分馏。该奖项反映了NSF的法定使命，并通过使用基金会的知识价值和更广泛的影响审查标准进行评估，被认为值得支持。