The Quality Control of Oceanic CO2 Measurements: Preparation and Distribution of Reference Materials

海洋二氧化碳测量的质量控制：标准物质的制备和分配

• 批准号: 2050280
• 负责人: Andrew Dickson
• 金额: $ 51.63万
• 依托单位: University of California-San Diego Scripps Inst of Oceanography
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2021
• 资助国家: 美国
• 起止时间: 2021-04-01 至 2025-03-31
• 项目状态: 未结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=2050280&HistoricalAwards=false
• 关键词: Quality; Control; Oceanic; CO2; Measurements

The goal of this project is to continue to provide a mechanism for the quality control of oceanic carbon dioxide measurements, in particular those that are made as part of international global programs. This will help to ensure that such measurements are comparable and accurate although made in different laboratories at different times. Such measurements are important components of global scale survey cruises such as those of the Global Ocean Ship-based Hydrographic Investigations Program (GO-SHIP), as well as playing a significant role in the quality control of ocean acidification measurements. The provision of reference materials to the international community helps to improve the overall quality of oceanic carbon data around the world both for field studies of the distribution of oceanic carbon, as well as for studies related to ocean acidification. It is a significant US contribution to global research infrastructure in this field. Numerous students are involved in, and receive training through, this program. To achieve the goal outlined above, the Scripps laboratory will prepare and certify reference materials for the following parameters of the oceanic carbon dioxide system in seawater: total dissolved inorganic carbon, total alkalinity, and pH. The reference materials for total dissolved inorganic carbon and for total alkalinity will be based on natural seawater, sterilized, bottled, and analyzed using appropriate reference methods for these parameters. Reference materials for pH are based on Tris buffers in synthetic seawater and calibrated using spectrophotometric pH measurements. In addition, the laboratory will distribute calibrated acid titrant for alkalinity measurements. Reference materials will be distributed to US and to international investigators to assist in the quality control of oceanic CO2 measurements. During the three years of this project, the laboratory expects to distribute about 30,000 bottles of reference material. These materials will also be used to provide test samples for use in collaborative studies of the analytical methods used to determine these various parameters.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

该项目的目标是继续为海洋二氧化碳测量的质量控制提供一种机制，特别是那些作为国际全球计划一部分的测量。这将有助于确保这些测量虽然在不同的时间在不同的实验室进行，但具有可比性和准确性。这些测量是全球海洋船舶水文调查计划（GO-SHIP）等全球尺度调查巡航的重要组成部分，同时在海洋酸化测量的质量控制方面发挥着重要作用。向国际社会提供参考材料有助于提高世界各地海洋碳数据的总体质量，无论是用于海洋碳分布的实地研究，还是用于与海洋酸化有关的研究。这是美国对该领域全球研究基础设施的重大贡献。许多学生都参与了这个项目，并通过这个项目接受了培训。为了实现上述目标，斯克里普斯实验室将为海水中海洋二氧化碳系统的以下参数准备和认证标准物质：总溶解无机碳、总碱度和ph。总溶解无机碳和总碱度的标准物质将以天然海水为基础，经过灭菌、装瓶，并使用适当的参比方法对这些参数进行分析。pH值的参考物质基于合成海水中的Tris缓冲液，并使用分光光度pH值测量进行校准。此外，实验室将分发校准的酸滴定剂用于碱度测量。参考材料将分发给美国和国际调查人员，以协助控制海洋二氧化碳测量的质量。在该项目的三年中，实验室预计将分发约30,000瓶标准物质。这些材料还将用于提供测试样品，用于用于确定这些不同参数的分析方法的合作研究。该奖项反映了美国国家科学基金会的法定使命，并通过使用基金会的知识价值和更广泛的影响审查标准进行评估，被认为值得支持。

项目成果

Technical note: Interpreting pH changes

• DOI: 10.5194/bg-18-1407-2021
• 发表时间: 2021-02-24
• 期刊: BIOGEOSCIENCES
• 影响因子: 4.9
• 作者: Fassbender, Andrea J.;Orr, James C.;Dickson, Andrew G.
• 通讯作者: Dickson, Andrew G.

Chemical speciation models based upon the Pitzer activity coefficient equations, including the propagation of uncertainties: Artificial seawater from 0 to 45 °C

基于 Pitzer 活度系数方程的化学形态模型，包括不确定性的传播：0 至 45°C 的人造海水

• DOI: 10.1016/j.marchem.2022.104095
• 发表时间: 2022
• 期刊: Marine Chemistry
• 影响因子: 3
• 作者: Humphreys, Matthew P.;Waters, Jason F.;Turner, David R.;Dickson, Andrew G.;Clegg, Simon L.
• 通讯作者: Clegg, Simon L.

Chemical speciation models based upon the Pitzer activity coefficient equations, including the propagation of uncertainties. II. Tris buffers in artificial seawater at 25 °C, and an assessment of the seawater ‘Total’ pH scale

基于 Pitzer 活度系数方程的化学形态模型，包括不确定性的传播。

• DOI: 10.1016/j.marchem.2022.104096
• 发表时间: 2022
• 期刊: Marine Chemistry
• 影响因子: 3
• 作者: Clegg, Simon L.;Humphreys, Matthew P.;Waters, Jason F.;Turner, David R.;Dickson, Andrew G.
• 通讯作者: Dickson, Andrew G.