Laboratory Chamber Studies on Gas-Phase Photooxidation and Aqueous Chemistry of Phenols and Methoxyphenols in Biomass Burning Organic Aerosol Formation

在化学学部环境化学科学项目的支持下，乔治亚理工学院的Nga Lee Ng和Rodney Weber及其学生将研究大气中生物质燃烧排放的有机气溶胶（悬浮在空气中的微小颗粒）的形成。了解这些颗粒如何形成对于评估它们对气候和人类健康的影响非常重要。火灾发生时，植物木质组织在高温下分解，释放出大量挥发性有机化合物（VOCs），包括酚类化合物。研究小组将研究这些酚类化合物在大气相关条件下如何反应形成有机颗粒，以及这些颗粒吸收光的能力。该团队还将开发和实施一个关于生物质燃烧烟雾颗粒的教学模块，让大亚特兰大地区的中学生了解与野火和空气污染有关的新科学概念。苯酚和甲氧基苯酚是生物质燃烧排放的非甲烷有机化合物的重要组成部分。这些重要的生物质燃烧排放物的氧化和进一步化学处理尚未在现实环境条件下进行系统研究。本项目将通过综合实验室实验，研究一系列酚类化合物在不同反应条件下气相氧化形成的二次有机气溶胶（SOA）及其随后的水相处理。气溶胶的光学性质也将被表征。这项研究的结果将为参数化释放到环境中的酚类化合物的气相和水相化学提供基础数据，并提供关于它们形成的气溶胶的增强信息。反过来，这些数据将对科学家开发用于解释这些有机气溶胶的大气模型有用。该奖项反映了美国国家科学基金会的法定使命，并通过使用基金会的知识价值和更广泛的影响审查标准进行评估，被认为值得支持。

With support from the Environmental Chemical Sciences Program in the Division of Chemistry Nga Lee Ng and Rodney Weber at Georgia Tech and their students will study the formation of organic aerosols (tiny particles suspended in the air) from biomass burning emissions in the atmosphere. Understanding how these particles form is important for evaluating their impact on climate and human health. During fires, the decomposition of woody tissues in plants at high temperatures releases a significant level of volatile organic compounds (VOCs), including phenolic compounds. The team will investigate how these phenolic compounds react under atmospherically relevant conditions to form organic particles, as well as the ability of these particles to absorb light. The team will also develop and implement an instruction module on particles from biomass-burning smoke to expose middle school students in the greater Atlanta area to new scientific concepts related to wildfires and air pollution. Phenols and methoxyphenols are a significant part of non-methane organic compounds emitted from biomass burning. The oxidation and further chemical processing of these important biomass burning emissions has not been systematically studied under realistic ambient conditions. Through comprehensive laboratory chamber experiments, this project will investigate secondary organic aerosol (SOA) formation from gas-phase oxidation of a set of phenolic compounds under different reaction conditions and their subsequent aqueous-phase processing. The optical properties of aerosols will also be characterized. Results from this study will provide fundamental data to parameterize the gas-phase and aqueous-phase chemistries of phenolic compounds released into the environment and provide enhanced information on the aerosols that they form. These data will, in turn, be useful to scientist developing atmospheric models designed to account for such organic aerosols.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.