Functional Catenes and Rotaxnes - The mechanical bond as a design element for the development of novel catalysts

功能性链烯和轮烷 - 机械键作为新型催化剂开发的设计元素

• 批准号: 339235880
• 负责人: Professor Dr. Jochen Niemeyer
• 金额: --
• 依托单位: Organische Chemie - AG Supramolekulare Chemie
• 依托单位国家: 德国
• 项目类别: Research Grants
• 资助国家: 德国
• 项目状态: 未结题
• 来源: https://gepris.dfg.de/gepris/projekt/339235880?language=en
• 关键词: Functional; Catenes; Rotaxnes; mechanical; bond

Mechanically interlocked molecules (MIMs), such as catenanes and rotaxanes, offer unique possibilities for the generation of novel catalysts. Within this research project, we propose an in-depth investigation of three specific features: a) The development of MIMs for cooperative catalysis, especially for combined transition-metal and organocatalysis, b) the use of MIMs for the generation of sterically demanding catalysts and c) the application of mechanically or topologically chiral MIMs in catalysis. This represents a further development of our earlier research in this area and will establish the mechanical bond as a new design-element in catalyst-development.

机械互锁分子（MIM），如索烃和轮烷，为新型催化剂的产生提供了独特的可能性。在这个研究项目中，我们提出了三个具体特点的深入调查：a）MIMs的协同催化，特别是过渡金属和有机催化的结合，B）MIMs的使用空间要求催化剂的生成和c）机械或拓扑手性MIMs在催化中的应用。这代表了我们在这一领域的早期研究的进一步发展，并将建立机械键作为催化剂开发中的新设计元素。