Pyridyl functionalized group 14 element compounds

吡啶基官能化14族元素化合物

• 批准号: 344889181
• 负责人: Privatdozentin Dr. Kornelia Zeckert
• 金额: --
• 依托单位: Institut für Anorganische Chemie
• 依托单位国家: 德国
• 项目类别: Research Grants
• 财政年份: 2017
• 资助国家: 德国
• 起止时间: 2016-12-31 至 2023-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/344889181?language=en
• 关键词: Pyridyl; functionalized; group; 14; element

Based on N-heteroaromatic ligands we recently succeeded in the stabilization and isolation of unusual molecular anionic organotinderivatives. The stabilization is achieved by an effective intramolecular coordination of the respective counter-ions. This concept of intramolecular coordination will be further employed to enable a defined and stepwise design of corresponding catenated tin compounds. Thus, the project comprises two major topics, including (i) the exploration of both synthetic routes and the possibility of conversion for small mono- or dianionic target molecules, e.g. stannylstannates and distannides, and (ii) the accessibility of larger intermetalloid cluster compounds through distannides and investigations towards their reactivity.

基于n -杂芳配体，我们最近成功地稳定和分离了不寻常的分子阴离子有机衍生物。稳定是通过分子内各反离子的有效配位来实现的。这种分子内配位的概念将被进一步用于确定和逐步设计相应的螯合锡化合物。因此，该项目包括两个主要主题，包括(i)探索小的单离子或二阴离子目标分子的合成路线和转化的可能性，例如，锡锡酸盐和二苯胺；（ii）通过二苯胺及其反应性研究获得较大的金属间簇化合物。