Materials development toward higher-voltage energy storage devices

面向更高电压储能设备的材料开发

• 批准号: 17F17349
• 负责人: 山田 淳夫
• 金额: $ 1.47万
• 依托单位: The University of Tokyo
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for JSPS Fellows
• 财政年份: 2017
• 资助国家: 日本
• 起止时间: 2017-11-10 至 2020-03-31
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-17F17349/
• 关键词: polyanions; layered oxides; Na-ion batteries; High-voltage cathode; Li-/Na-ion batteries

The goal of this JSPS fellowship is to identify new high-potential cathode materials for sodium-ion batteries. To this end, we studied the electrochemical properties of a Na-based heteropolyanionic SO4-PO3F solid-solution Na2Fe(SO4)2-x(PO3F)x.2H2O. The PO3F unit has not been studied as a polyanion for cathode materials so far and we were interested in its inductive effect and its impact on electrochemical performances. Galvanostatic cycling revealed elevated redox potentials for the PO3F polyanion. This would open the pathway to a new class of high-potential cathode materials. However, one drawback of this functional group is its low thermal stability. Therefore, we try to find additional synthesis routes to ensure an easy and reproducible preparation method of this compound.A second project consists of the electrochemical and structural characterization of a Na-based layered oxide containing Ti4+ and Co2+, which displays a large hysteresis during Na (de)intercalation suggesting a spin transition of Co2+ upon oxidation. We are using a multi-angle approach with complementing characterization methods such as ex situ soft and hard X-ray absorption, magnetic measurements and galvanostatic intermittent titration technique (GITT) experiments to understand the underlying redox mechanism. Furthermore, we performed Density Functional Theory calculations to complement the experimental work with a theoretical viewpoint. The respective publication is under preparation.

该JSPS奖学金的目标是为钠离子电池确定新的高电位阴极材料。为此，我们研究了Na基杂多阴离子SO 4-PO 3F固溶体Na 2Fe（SO 4）2-x（PO 3F）x·2 H2O的电化学性质。PO 3F单元还没有被研究作为阴极材料的聚阴离子，我们感兴趣的是它的诱导效应和它对电化学性能的影响。恒电流循环显示PO 3F聚阴离子的氧化还原电位升高。这将为一类新的高电位阴极材料开辟道路。然而，该官能团的一个缺点是其低的热稳定性。因此，我们试图寻找其他的合成路线，以确保该化合物的制备方法简单，重复性好。第二个项目包括含Ti 4+和Co 2+的Na基层状氧化物的电化学和结构表征，其在Na（脱）嵌入过程中显示出很大的滞后，表明Co 2+在氧化时的自旋跃迁。我们正在使用多角度的方法与补充表征方法，如非原位软X射线和硬X射线吸收，磁性测量和恒电流间歇滴定技术（GITT）实验，以了解潜在的氧化还原机制。此外，我们进行了密度泛函理论计算，以补充理论观点的实验工作。有关出版物正在编写中。

项目成果

Redox-Driven Spin Transition in a Layered Battery Cathode Material

• DOI: 10.1021/acs.chemmater.8b04775
• 发表时间: 2019-03
• 期刊: Chemistry of Materials
• 影响因子: 8.6
• 作者: Eriko Watanabe;Wenwen Zhao;A. Sugahara;Benoit Mortemard de Boisse;Laura Lander;D. Asakura;Y. Okamoto;T. Mizokawa;M. Okubo;A. Yamada

Highly reversible Oxygen-redox Chemistry at 4.1 V in Na4/7[Vac1/7Mn6/7]O2 (Vac: Mn vacancy)

Na4/7[Vac1/7Mn6/7]O2 中 4.1 V 下的高度可逆氧氧化还原化学（Vac：Mn 空位）

• 发表时间: 2018
• 期刊: Advanced Energy Materials
• 影响因子: 27.8
• 作者: Benoit Mortemard de Boisse;Shin-ichi Nishimura;Eriko Watanabe;Laura Lander;Akihisa Tsuchimoto;Jun Kikkawa;E. Kobayashi;Daisuke Asakura;Masashi Okubo;Atsuo Yamada
• 通讯作者: Atsuo Yamada

Synthesis, crystal structure and possible proton conduction of Fe(H2PO4)2F

Fe(H2PO4)2F的合成、晶体结构和可能的质子传导

• DOI: 10.1016/j.ssi.2019.05.019
• 发表时间: 2019
• 期刊: Solid State Ionics
• 影响因子: 3.2
• 作者: Zihan Ma;Laura Lander;Shin-ichi Nishimura;Chihoko Fukakusa;Teppei Yamada;Masashi Okubo;Atsuo Yamada
• 通讯作者: Atsuo Yamada

Fe-based SO4-PO3F heteropolyanionic cathodes for sodium-ion batteries

钠离子电池用铁基SO4-PO3F杂多阴离子正极

• 发表时间: 2018
• 作者: Laura Lander;Shin-ichi Nishimura;Benoit Mortemard de Boisse;Masashi Okubo;Atsuo Yamada
• 通讯作者: Atsuo Yamada

Stability of conductive carbon additives in 5?V-class Li-ion batteries

5V级锂离子电池中导电碳添加剂的稳定性

• DOI: 10.1016/j.carbon.2019.11.051
• 发表时间: 2020
• 期刊: Carbon
• 影响因子: 10.9
• 作者: Ko Seongjae;Yamada Yuki;Lander Laura;Yamada Atsuo
• 通讯作者: Yamada Atsuo