Developmental Study of New Functionality Materials For Energy Storage and Transport.

作为用于有机金属、TTF和放射性的乙烯基的新电子捐赠者，拥有1、3-二聚氰胺-2-酰亚胺Moietes已被合成，其CT的电特性的复合体也已被研究。他们的CT复合体与几种电子接收器，TCNQ揭示了300 ° K = 16 S/cm的高导电性的1 ： 1双（ 1，3-二氟苯基）<sigma>复合体。“organic metal”。新的放射性物质，在特定的（3）放射性物质中，被期望作为一种不可取的电子捐赠者，因为新的有机金属类型、高电子捐赠能力和高协同平面性。（4）放射性物质-TCNQ（或TCNQE_4 ） CT复合体和PF 6和C10_4盐的（4）放射性离子在压缩颗粒或crystal状态中被调查。他们对O的可能性提出了建议。 ... More organic metals。为混合的valency状态做好准备的可能性也被建议：一个捐赠者接受者Norbornadiene已经准备好了，并且在受评估的实验中储存光能量的有效性。2，3-Dicyano-4，5，6-三甲基Norbornadiene展示了最佳的有效性。北苯二烯与相应的四聚氰胺的化学转化在隔离下花费了5摩尔/米^2天，而典型的运行接近理论上的一个， 6摩尔/米^2天。《关于不同基因催化剂用于能源释放过程的开发研究》已经通过一系列基础研究，包括金属元素筛选、金属催化循环版本的反应机制、催化剂的不流动化和更持久的方法。间接地，一种极好的非同源催化剂，用于三甲基四环素的循环版本已经找到，其中揭示了许多优点的属性，高活动，低的去激活率和恢复活性的能力，通过加热使用的催化剂在真空下的恢复。Less（低）

As new electron donors for organic metals, vinylogues of TTF and radialenes possessing 1,3-dithiol-2-ylidene moieties have been synthesized, and electric propeties of their CT-complexes have been studied. Among their CT-complexes with several electon acceptors, the 1 : 1 complex of bis( 1,3-dithiafulvenyl ) with TCNQ revealed high electric aonductivity of <sigma> 300゜K = 16 S/cm. Additionally, the electric conductivity of the complex showed a temperature dependence ressmbling that of metal, indicating that the complex is undoubtedly " organic metal ". The new radialenes, in particular (3)radialene, are expected as desirable electron donors for new types of organic metals, because of their high electron-donating ability and of their high co-planarity.The electlric properties of (4)radialene-TCNQ ( or TCNQE_4 ) CT complex and of the PF6 and C10_4 salts of (4)radialene cation radical were investigated in compressed pellet or crystal state, and their results suggested the possiblility of o … More rganic metals. A possibility preparing the mixed valency state was also suggested.A number of the donor-acceptor norbornadienes has been prepared, and their efficiencies of storing light energy under solar insolation have been assessed experimentally.2,3-Dicyano-4,5,6-trimethylnorbornadiene showed the fighest efficiency. The chemical conversion of the norbornadiene to the corresponding quadricyclane under insolation was 5 mol/m^2 day for a typical run which was close to the theoretical one, 6 mol/m^2 day. The development study of the heterogeneous catalyst for the energy-releasing process has been performed begining with a series of fundamental studies including screening of metal elements, reaction mechanisms of metal catalysed cycloreversion, methods for immobilization of catalyst and so forth. Consequently, an excellent heterogeneous catalyst for the cycloreversion of trimethyldicyanoquadricyclane has been found, which revealed many prominent properties, high activity, small deactivation rate and moreover ability of restoration of activity by heating the used catalyst under vacuo. Less