Integration of Photoredox-active Complexes in Redox-active Polymers for Light-induced Charging and Discharging by Additional Integrated Molecular Catalysts (B02)

通过额外的集成分子催化剂将光氧化还原活性复合物集成到氧化还原活性聚合物中以实现光诱导充电和放电（B02）

• 批准号: 407426708
• 金额: --
• 依托单位: Institut für Organische Chemie und Makromolekulare Chemie
• 依托单位国家: 德国
• 项目类别: CRC/Transregios
• 资助国家: 德国
• 项目状态: 未结题
• 来源: https://gepris.dfg.de/gepris/projekt/407426708?language=en
• 关键词: Integration; Photoredox; active; Complexes; Redox

B02 will explore light-induced electron-transfer between PS/PS-CAT based on noble metal free building blocks and redox-active polymers. Effects of the polymer structure and morphology on the efficiency of the overall redox cascade will be explored. Light driven reductive charging of redox polymers will be performed and coupled to AOC using PS-CAT dyads. Robust conducting polymers will be oxidized to fuel the light driven HER catalysis with PS-CAT dyads. Charged polymers will be discharged by appropriate catalysts or electrodes enabling the development of a polymeric Z-scheme.

B02将探索基于无贵金属构建块和氧化还原活性聚合物的PS/PS- cat之间的光诱导电子转移。将探讨聚合物结构和形态对整个氧化还原级联效率的影响。光驱动的氧化还原聚合物的还原充电将被执行，并使用PS-CAT二元偶联到AOC。坚固的导电聚合物将被氧化，为PS-CAT二元体的光驱动HER催化提供燃料。带电的聚合物将通过适当的催化剂或电极放电，从而形成聚合物z型方案。