Integration of Photoredox-active Complexes in Redox-active Polymers for Light-induced Charging and Discharging by Additional Integrated Molecular Catalysts (B02)

B02将探索基于贵金属自由构建块的PS/PS-CAT与氧化还原活性聚合物之间的光诱导电子转移。将探索聚合物结构和形态对整个氧化还原级联效率的影响。氧化还原聚合物的光驱动还原充电将被执行，并使用PS-CAT二元组与AOC偶联。强韧的导电聚合物将被氧化，以支持PS-CAT二元组分的光驱动催化。带电聚合物将由适当的催化剂或电极放电，从而形成聚合物Z-方案。

B02 will explore light-induced electron-transfer between PS/PS-CAT based on noble metal free building blocks and redox-active polymers. Effects of the polymer structure and morphology on the efficiency of the overall redox cascade will be explored. Light driven reductive charging of redox polymers will be performed and coupled to AOC using PS-CAT dyads. Robust conducting polymers will be oxidized to fuel the light driven HER catalysis with PS-CAT dyads. Charged polymers will be discharged by appropriate catalysts or electrodes enabling the development of a polymeric Z-scheme.