Control of Spin States at Metal Centers through Fluorine-Specific Interactions in the Secondary Coordination Sphere (B02)

通过二次配位球中氟特异性相互作用控制金属中心的自旋态 (B02)

• 批准号: 414779824
• 金额: --
• 依托单位: Institut für Anorganische Chemie (IAC)
• 依托单位国家: 德国
• 项目类别: Collaborative Research Centres
• 财政年份: 2019
• 资助国家: 德国
• 起止时间: 2018-12-31 至 2021-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/414779824?language=en
• 关键词: Control; Spin; States; Metal; Centers

Within this project, we want to develop ligand systems that contain C-F bonds at specific positions. Such C-F units will be used to generate targeted Fluorine-Specific Interactions in the secondary coordination sphere of 3d metal centers, which in turn will control the spin states at the transition metal center. The immediate goal of this project is the switching of spin states through external stimuli. A long-term goal is the modification of the reactivity at the transition metal center through a control of its spin state.

在这个项目中，我们希望开发在特定位置包含C-F键的配体系统。这样的C-F单元将被用来在3D金属中心的次级配位球中产生有针对性的氟特定相互作用，这反过来将控制过渡金属中心的自旋态。这个项目的直接目标是通过外部刺激来切换自旋状态。一个长期的目标是通过控制过渡金属中心的自旋态来改变其反应性。