Controlling the Activation of CO2 and H2 by Fluorine-Specific Interactions at Lewis-acidic Interfac-es (B05)

B5|FREI项目的重点是金属氧氟化物作为多相催化剂的适用性。通过系统地调节氧化锌中氟化物的浓度，控制了表面的路易斯酸度。此外，体相中的氟化物还起到电子促进剂的作用。理解和关联氟诱导的相互作用与激活二氧化碳和氢气的能力是将这一概念应用于其他材料和反应的关键步骤。

The project B5|Frei focuses on the suitability of metal oxo-fluorides as heterogeneous catalysts. By systematically adjusting the fluoride concentration in ZnO, the Lewis-acidity on the surface is controlled. Further, fluoride located in the bulk acts also as electronic promoter. The understanding and correlation of the fluoride induced interactions with the ability of activating CO2 and H2 serves as key step to apply this concept to other materials and reactions.