Unconventional syntheses to manipulate magnetocaloric MAB phases and antiperovskites (B03)

含有非关键元素的层状块状固体（MAB相）和具有可变晶体结构的固体（反钙钛矿碳化物，氮化物和碳氮化物），已知或预测为具有高磁化强度的稳定磁热材料，将通过微波加热和湿化学技术（溶胶-凝胶和液氨）合成为粉末。指导原则将与B02一致，例如通过掺杂来操纵转变温度。进一步的目标化合物（A05）被预测为稳定的磁热学（Fe3AlB4, Fe3CoB2, Mn3SnC, Co3GaN）将被包括（B05）和磁表征（B01）。

Layered bulk solids (MAB phase) and solids with variable crystal structures (antiperovskite carbides, nitrides and carbonitrides) which contain non-critical elements, known or predicted as stable magnetocaloric materials with high magnetization, will be synthesized as powder by using microwave heating and wet chemical-based techniques (sol-gel and liquid ammonia). Guiding principles will be in line with B02, such as manipulating transition temperatures by doping. Further target compounds that have been predicted (A05) as stable magnetocalorics (Fe3AlB4, Fe3CoB2, Mn3SnC, Co3GaN) will be included (B05) and magnetically characterized (B01).