Effect of Molecular Structure on Radiation-Induced Processes in Condensed Phase

溶液中的化学过程受到溶剂浓度和密度的微观波动的影响。在过去的几十年里，由于理论分析和实验分析的困难，对波动效应的研究已经进行了尝试，但进展相对较少。在本研究中，我们关注电离辐射在二元溶液中引起的化学过程，因为电离和随后的化学事件被认为是受研究溶液物理性质波动的敏感影响。在调查了与本研究有关的文献后，我们注意到，先前对涨落的理论处理是基于对解组成描述的一些限制性近似。由于这个问题是基础性和广泛性的，我们花了一些时间来构建严格的理论基础，在此基础上，我们应该研究受化学过程影响的光散射等现象。我们已经成功地推导出一个一般表达式来评价化学过程对溶液波动的影响。

Chemical processes in solutions are under the influence of microscopic fluctuations of concentration and density of solvents. The study of the effect of the fluctuation has been attempted in the past several decades with relatively little progress due the difficulty of both theoretical and experimental analyzes of the subject.In the present research we are concerned with chemical processes induced by ionizing radiation in binary solutions because the ionization and ensuing chemical events are considered to be sensitively affected by the fluctuation of physical properties of the solution under study.Upon surveying the literature related to the present research we have noted that the preceding theoretical treatment of the fluctuation is based on some restrictive approximation with regard to the description of the composition of solutions. Since the problem is fundamental and extensive, we spent some time to construct rigorous theoretical bases, upon which such phenomena as the light scattering influenced by chemical processes should be investigated.We have succeeded in deriving a general expression to assess the effect of chemical processes upon the fluctuation in solutions.