Soft-Template-Assisted On-Water Surface Synthesis of 2D Polymers (A03)

软模板辅助二维聚合物的水面合成 (A03)

• 批准号: 443783564
• 金额: --
• 依托单位: Professur für Molekulare Funktionsmaterialien
• 依托单位国家: 德国
• 项目类别: Collaborative Research Centres
• 资助国家: 德国
• 项目状态: 未结题
• 来源: https://gepris.dfg.de/gepris/projekt/443783564?language=en
• 关键词: Soft; Template; Assisted; Water; Surface

The project will focus on the on-water surface synthesis of single-/few-layer (< 10 layers) porphyrin-based 2DPs with large crystalline domains (μm2) via dynamic covalent bonds by soft-template-assisted method. Moreover, the corresponding structural characterization and reaction mechanism will be elucidated. Special focus will be given to the understanding of the role of soft-templates for the synthesis of 2DPs and to address the controllable stacking of the monomers, the defect repairing, the enhancement of the polymerization degree, etc.

该项目将致力于利用软模板辅助的方法，通过动态共价键在水中合成单层/少层(&lt；10层)的具有大结晶区(μm2)的卟啉基2DPs。此外，还将阐明相应的结构表征和反应机理。重点是了解软模板在2DPS合成中的作用，并解决单体的可控堆积、缺陷修复、聚合度的提高等问题。