Design of highly functional catalysts based on acid. base combination chemistry

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Rational design of catalysts is very important to control not only reactivity of target reactions but also chemoselectivity, stereoselectivity, regioselectivity, enantioselectivity, and substrate selectivity. Enzymes almost perfectly control target reactions even in vivo. On the other hand, small molecule artificial catalysts cannot perfectly control reactions. In this research project, the development of new acid. base combined catalysts was performed to attain high level of catalytic functions. As results, we succeeded in the development of several high functional catalysts based on acid. base combination chemistry.