Synthesis and organic photovoltaic applications of fully conjugateddonor-acceptor diblock copolymers

全共轭供体-受体二嵌段共聚物的合成及有机光伏应用

• 批准号: 23850004
• 负责人: NAKABAYASHI Kazuhiro
• 金额: $ 2.08万
• 依托单位: Yamagata University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Research Activity Start-up
• 财政年份: 2011
• 资助国家: 日本
• 起止时间: 2011 至 2012
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-23850004/
• 关键词: 高分子合成; 自己組織化; 太陽電池

Fully conjugated donor-acceptor block copolymers were synthesized for the candidate of non-fullerene acceptor materials. The obtained block copolymers showed the good acceptor and wide light-harvesting properties. The all-polymers solar cells, in which the active layers were respectively prepared from poly(3-hexylthiophene) and the obtained block copolymers as donor and acceptor materials, achieved the power conversion efficiency of 1.6%. These results demonstrated that fully conjugated donor-acceptor block copolymers had a huge potential for the non-fullerene acceptor material.

合成了完全共轭的供体-受体嵌段共聚物，作为非富勒烯受体材料的候选者。所得嵌段共聚物具有良好的受体和宽广的捕光性能。以聚(3-己基噻吩基)和嵌段共聚物为供给体和受体体制备有源层的全聚合物太阳能电池，其功率转换效率达到1.6%。这些结果表明，完全共轭的给体-受体嵌段共聚物在非富勒烯受体材料中具有巨大的潜力。

项目成果

Fully Conjugated Donor-Acceptor Block Copolymers Incorporating Poly(naphthalene bisimide) Segments for Photovoltaic Applications

用于光伏应用的包含聚萘双酰亚胺片段的完全共轭供体-受体嵌段共聚物

• 发表时间: 2012
• 作者: 中林千浩;森秀晴;Kazuhiro Nakabayashi and Hideharu Mori
• 通讯作者: Kazuhiro Nakabayashi and Hideharu Mori

ナフタレンビスイミド骨格を有する共役系ドナー・アクセプター型ブロック共重合体

具有萘双酰亚胺骨架的共轭供体-受体型嵌段共聚物

• 发表时间: 2012
• 作者: 中林千浩;森秀晴
• 通讯作者: 森秀晴

All-Polymer Solar Cells Based on Fully Conjugated Block Copolymers Composed of Poly(3-hexylthiophene) and Poly(naphthalene bisimide) Segments

• DOI: 10.1021/ma302170e
• 发表时间: 2012-12
• 期刊: Macromolecules
• 影响因子: 5.5
• 作者: Kazuhiro Nakabayashi;H. Mori

All Conjugated Donor-Acceptor Block Copolymers Incorporating Poly(naphthalene bisimide) Segments

所有包含聚萘二酰亚胺片段的共轭供体-受体嵌段共聚物

• 发表时间: 2012
• 作者: 中林千浩;森秀晴;中林千浩;Kazuhiro Nakabayashi
• 通讯作者: Kazuhiro Nakabayashi

Electron-transporting Semiconducting Materials for All-polymer Solar Cells

用于全聚合物太阳能电池的电子传输半导体材料

• 发表时间: 2012
• 作者: 中林千浩;森秀晴
• 通讯作者: 森秀晴