Task-specific ionic liquids and their Group 10 metal coordination complexes for Interface-enhanced catalysis (B01)

用于界面增强催化的特定任务离子液体及其第10族金属配位化合物（B01）

• 批准号: 456886096
• 金额: --
• 依托单位: Lehrstuhl für Anorganische und Allgemeine Chemie
• 依托单位国家: 德国
• 项目类别: Collaborative Research Centres
• 资助国家: 德国
• 项目状态: 未结题
• 来源: https://gepris.dfg.de/gepris/projekt/456886096?language=en
• 关键词: Task; specific; ionic; liquids; their

Project B01 focuses on the design and synthesis of functionalised and task-specific ILs, with the aim (i) to tailor support/IL interfaces and (ii) to develop electrocatalytically active interface-enhanced SILPs. The latter concept will combine catalytic functionalities operating at both the gas/IL and the IL/solid interfaces for the electrochemical production of hydrogen from water (or protons) and the hydrogenation of divers C=C and C=O moieties in selected substrates. These two processes shall be controlled by the incorporation of identical task-specific structural motifs in the IL and in the active transition metal catalyst. The long-term objective will be the direct electrocatalytic hydrogenation of substrates in a ‘tandem-like’ system.

项目B 01专注于功能化和特定任务的离子液体的设计和合成，目的是（i）定制支持/离子液体界面和（ii）开发电催化活性界面增强的SILP。后一种概念将结合联合收割机催化功能，其在气体/IL和IL/固体界面处操作，用于从水（或质子）电化学生产氢和在所选底物中氢化多种C=C和C=O部分。这两个过程应通过在IL和活性过渡金属催化剂中引入相同的任务特异性结构基序来控制。长期的目标将是直接电催化氢化的基板在一个“串联”系统。