SYNTHESIS OF POLYMERS WITH A MULTI-DIMENSINALLY CONTROLLED STRUCTURE BY SOLID-STATE POLYMERIZATION

在这个研究项目中，我们已经通过固体状态聚合物化和基于聚合物晶体工程的有机材料设计来控制聚合物结构。Crystalline材料的结构和性能是基于聚合物Crystal工程的设计。水晶石材料的结构和特性是通过各种间分子相互作用（如氢键、*... *、CH/*、CH/O和卤素相互作用）设计的。我们已经澄清了拓扑化学聚合物的1，3-二烯单-和二碳基酸衍生物的特性和机制，以适当的方式。We have also proposed the topochemical polymerization principles for diene monomers on the basis of the crystallographic data accumulated for the construction of molecular packing appropriate for 5A stacking in order to facilitate the topochemical polymerization in the crystalline state。我们在控制聚合物链结构（包括战术、分子重量和阶梯结构）的情况下成功了，也是聚合物晶体结构，作为利用拓扑化学聚合物生成的分层聚合物晶体的有机中间系统很好。

In this research project, we carried out polymer structure control with a multi-dimensionally controlled structure by solid-state polymerization and organic material design based on polymer crystal engineering. The structures and properties of crystalline materials were design based on polymer crystal engineering. The structures and poperties of crystalline materials were designed using pre-organized molecules through various intermolecular interactions such as hydrogen bonds, *・・・*, CH/*, CH/O, and halogen interactions. We have clarified the features and mechanisms of the topochemical polymerization of 1,3-diene mono- and dicarboxylic acid derivatives, respectively. We have also proposed the topochemical polymerization principles for diene monomers on the basis of the crystallographic data accumulated for the construction of molecular packing appropriate for 5 A stacking in order to facilitate the topochemical polymerization in the crystalline state. We succeeded in the control of polymer chain structure including tacticitiy, molecular weight, and ladder structure, and also polymer crystal structures, as well as the organic intercalation system using layered polymer crystals obtained by the topochemical polymerization