NMR spectroscopic tools to detect Brønsted/Lewis acid-base preorganization in photocatalysis (B03)

该项目的主要目标是检测、合理化和设计光催化中氢键和Lewis酸碱相互作用的影响。先进的核磁共振波谱方法与来自合成合作伙伴的精选和设计的模型系统相结合，将用于解决光催化中孤立的氢键、协作性效应和扩展的氢键网络的影响。此外，对于到目前为止更灵活和更少定向的Lewis酸碱相互作用，应该测试核磁共振光谱工具，以开发一种在光催化中获得基于结构的Lewis酸碱效应的途径。

The main goal of the project is to detect, rationalize and design the effect of H-bonds and Lewis-acid/base interactions in photocatalysis. Advanced NMR-spectroscopic methods in combination with selected and designed model systems from synthetic collaboration partners will be used to address the impact of isolated H-bonds, cooperativity effects and extended H-bond networks in photocatalysis. In addition, for the by far more flexible and less directed Lewis acid base interactions NMR spectroscopic tools shall be tested to develop an access to structure-based Lewis acid base effects in photocatalysis.