New Development of Organic Electrochemistry
New Development of Organic Electrochemistry
批准号:
05235101
负责人:
OSA Tetsuo
金额:
$22.21万
依托单位:
依托单位国家:
日本
项目类别:
Grant-in-Aid for Scientific Research on Priority Areas
财政年份:
1993
资助国家:
日本
项目状态:
已结题
起止时间:
1993 至 1995
中文摘要
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英文摘要
Investigation of this group {X00} playd a function of managemet group for this rescarch project. The group consisted of 6 advisory and 5 executive members exerted an effective propulsion of the research project in close cooperation of four research groups (A01-A04) , getting advice by advisory members.1.Research Subjects and Ressults The project was set up by four research subjects : 1) Design and Control of Electron-transfer Reaction Fields (A01), 2) Electrogenerated Unusual Active Species (A02), 3) Development of Mediator Reactions (A03), and 4) New Development of Electron Transfer in Coordination Compounds (A04). The project was pursued by 29 project members and 91 public-applicant members for 1995. In October, 1996, we evaluated a fruitful success in all the subjects which developed not only organic electrochemistry remarkably but also contributed to build many organic reaction systems being unable to perform by conventional organic chemistry methods. Furthermore, the results was c … More ontributed to build interdisciplinary areas with coordination chemistry and biochemistry. Its shoul be mentioned that asymmetric or enantioselective electrolysis was achieeved over our intial proposal which would become to a new tool in organic chemistry.2.Opening of Whole Members' Meeting and Open Symposia Six whole members' meetings and 5 open symposia were connectively opened as well as many times of meetings for management group and each research subject groups. It is noticed that the group leaders arranged actively to maintain informal four cooperative research systems concerning reactive metal surface electrode, electrode reaction by physical method, biofunctionality throughelectron transfer and chiral synthesis.3.Printing Meterials Research reports composed of each 2 pages in Japanese and English versions by all the members were published in the end of each years and a collective research report by 4 English pages of every member was done in December, 1996. Abstracts at the whole members' meetings and open symposia were not only distributed to the members and other participants every time, but 12 times of news letters relating the research were also distributed to the members. An English book "New Challenges in Organic Electrochemistry" which was applied a support to Monbusho is being prepared to publish in February, 1998. Less
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Tetsiuo Osa: "Enantioselective,Electrocatalytic Lactonization of Methyl-substituted Diols on a TEMPO-modified Graphite Felt Electrode in the Presence of(-)-Sparteine" Chemistry Letter. 1043-1044 (1996)
Tetsiuo Osa:“在(-)-金雀花碱存在下,甲基取代二醇在 TEMPO 改性石墨毡电极上的对映选择性电催化内酯化”化学快报。
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Yoshihito Kunugi: "Preparation of Hydrophobic Zinc and Lead Electrodes and Their Application to Electroreduction of Organic Compounds" Journal of Electroanalytical Chemistry. 356. 163-169 (1993)
Yoshihito Kunugi:“疏水性锌和铅电极的制备及其在有机化合物电还原中的应用”电分析化学杂志。
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Sigeru Torii: "Electroreduction of 5-Chloro-7-nitrobenzofuran Derivative,a Facile Access to a Key Intermediate for ACTA Inhibitors" Synlett. 68 (1994)
Sigeru Torii:“5-氯-7-硝基苯并呋喃衍生物的电还原,一种轻松获得 ACTA 抑制剂关键中间体的方法”Synlett。
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Tsutomu Nonaka: "Product-Selectivity Control in an Electroorganic Process by Temperature.Electroreduction of Acetophenone" Chemistry Letter. 862-862 (1995)
Tsutomu Nonaka:“通过温度控制有机电过程中的产物选择性。苯乙酮的电还原”化学快报。
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Tetsuo Osa: "Preparative, Electroenzymatic Reduction of NAD^+ to NADH on a Thin Poly (Acrylic Acid) Layr-Coated Graphite Felt Electrode Coimmobilizing Ion-paired Methyl Viologen-Cation-Exchange Polymer and Diaphorase" Chemistry Letters. 1996. 1093-1094
Tetsuo Osa:“在薄聚(丙烯酸)层涂覆的石墨毡电极上将 NAD^ 制备电酶还原为 NADH,共固定离子对甲基紫精-阳离子交换聚合物和心肌黄酶”化学快报。
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共 95 条
Development of Mediator Reaction
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批准号:05235102
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项目类别:Grant-in-Aid for Scientific Research on Priority Areas
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资助金额:$59.07万
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财政年份:1993
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负责人:OSA Tetsuo
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依托单位:
Development of Molecular Recognition Sensing Systems Using Frmation of Intra- and Inter-moleulcar Excimer
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批准号:01470086
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项目类别:Grant-in-Aid for General Scientific Research (B)
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资助金额:$3.9万
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财政年份:1989
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负责人:OSA Tetsuo
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依托单位: