Reactive Organometallics
Reactive Organometallics
批准号:
05236105
负责人:
MURAHASHI Shun-ichi
金额:
$80.83万
依托单位:
依托单位国家:
日本
项目类别:
Grant-in-Aid for Scientific Research on Priority Areas
财政年份:
1993
资助国家:
日本
项目状态:
已结题
起止时间:
1993 至 1996
中文摘要
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英文摘要
Aiming to acquire innovative method of chemical transformation for the future, the present research project designed and produced reactive organometallics that suit appropriate purposes, and placed emphasis on clarifying their function of catalysis and molecular recognition and examining their possibility of working as functional materials. The following research groups were set up depending on the research theme :A) Reactive Organometallics of Transition Metals (S.-I.Murahashi)B) Reactive Organometallics of Non-transition Metals (R.Okazaki)C) Organometallics of organic Active Intermediates (Y.Yamamoto)D) Catalysis of Reactive Organometallics (A.Yamamoto)E) Molecular Recognition of Reactive Organometallics (Y.Moro-oka)110 researchers in total engaged in this project and in consequence, fruitful results that are original enough to promoto the introduction of the leading technology were obtained in the field of organometallic chemistry, organic synthesis, catalysis, and functional materials.The meetings of head of research group and evaluation group were held twice a year (seven in total) to promote and to generalize the project. Open symposiums were held 7 times to exchange lively and meaningful opinions between researchers, and about 200 people including researchers and those from private enterprises from outside took part in every symposium. The gist of the symposium was published each time and was distributed to all concerned. In addition, we issued public relations bulletins 8 times and also filed a report on our three-year research "Reactive organometallics-Synthesis and Function- " in English and distributed it to the Ministry of Education, Science, Culture and Sports, and researchers at large to make our results widely known at home as well as abroad.
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R.Okazaki: "The First Rotational Isomers of Stable Selenoaldehydes and Their 1-Tungsten Complex" Angew.Chem.,Int.Ed.Engl.35. 660-662 (1996)
R.Okazaki:“稳定硒醛及其 1-钨配合物的第一个旋转异构体”Angew.Chem.,Int.Ed.Engl.35。
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Y.Moro-oka: "Deoxygenative Reduction of Diruthenium Carbonyl Complexes(^5-C_5H_4R)_2Ru_2(-CH_2)_n(-CO)_<2-n>(CO)_2(n=1,2;R=H,Me)" Organometallics. 15. 2548-2553 (1996)
Y.Moro-oka:“二钌羰基配合物的脱氧还原(^5-C_5H_4R)_2Ru_2(-CH_2)_n(-CO)_<2-n>(CO)_2(n=1,2;R=H,
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Yamamoto,Yoshinori: "Palladium Catalyzed Addition of Activated Methylene and Methyne Compounds to Allenes" Journal of the American Chemical Society. 116. 6019-6020 (1994)
Yamamoto,Yoshinori:“钯催化活化亚甲基和次甲基化合物与二烯的加成”,美国化学会杂志。
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Moro-oka,Yoshihiko: "A reaction mimic of tyrosine hydroxylase:hydroxylation of a phenoxo ferric complex to a catecholato complex with mCPBA" Journal of the American Chemical Society. 115. 9335-9336 (1993)
Moro-oka,Yoshihiko:“酪氨酸羟化酶的反应模拟:用 mCPBA 将苯氧铁复合物羟基化为儿茶酚复合物”美国化学会杂志。
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Yamamoto,Yoshinori: "Mediation of the reactivity of the strong Lewis acid titaniumtetrachloride by complexation with XPh_3 (X=arsenic,antimony,bismuth)" The Journal of Organic Chemistry. 58. 4783-4784 (1993)
Yamamoto,Yoshinori:“通过与 XPh_3(X=砷、锑、铋)络合调节强路易斯酸四氯化钛的反应性”有机化学杂志。
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共 43 条
Exploitation of Catalytic Biomimetic Oxidation Reaction
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批准号:15550097
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项目类别:Grant-in-Aid for Scientific Research (C)
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资助金额:$2.05万
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财政年份:2003
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负责人:MURAHASHI Shun-ichi
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依托单位:
Development of Selective Catalytic Reactions by Simulation of the Function of Hepatic Flavoenzyme
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批准号:08455428
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项目类别:Grant-in-Aid for Scientific Research (B)
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资助金额:$5.06万
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财政年份:1996
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负责人:MURAHASHI Shun-ichi
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依托单位:
Reactive Organometallics of Transition Metals
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批准号:05236104
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项目类别:Grant-in-Aid for Scientific Research on Priority Areas
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资助金额:$44.03万
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财政年份:1993
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负责人:MURAHASHI Shun-ichi
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依托单位:
海外基金