Dimensional Control of New Magnetic Coordination Compounds

新型磁配位化合物的尺寸控制

• 批准号: 16550062
• 负责人: MIKURIYA Masahiro
• 金额: $ 1.54万
• 依托单位: Kwansei Gakuin University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (C)
• 财政年份: 2004
• 资助国家: 日本
• 起止时间: 2004 至 2006
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-16550062/
• 关键词: dinuclear complexes; polynuclear complexes; metal complexes; meta-metal bonds; bridging ligands; carboxylato-bridges; magnetic properties; self-assembly; 酸素錯体; カルボキシラト架橋; ラジカル; ルテニウム; シッフ塩基; シアノ基; 一次元錯体; カルボン酸銅

New magnetic coordination compounds having zero-, one-, two-, and three-dimensional assemblies were prepared by the combination of mononuclear and dinuclear metal complexes and bridging ligands. These compounds were characterized by temperature dependence of the magnetic susceptibility, infrared and diffused reflectance spectra, and single-crystal X-ray crystallography. 4,4'-Dipyridyl disulfide reacted with mononuclear metal complexes to afford one-dimensional coordination polymers made up of rhomboidal units, zig-zag chains, and cyclic compounds for zinc(II), manganese(II), cobalt(II) and nickel(II) cases. This bridging ligand reacted with copper(II) carboxylates to form one-dimensional coordination polymers with repeated rhomboid or porous honey-comb-like structures, showing an antiferromagnetc behavior. The combination of dinuclear ruthenium carboxylates and N, N'-didentate ligands afforded tetranuclear and one-dimensional polynuclear complexes depending on the reaction condition. With octacyanotungstate, one-, two-, and three-dimensional assemblies were attained and these compounds show a ferromagnetic behavior. Cyano briding ligands afforded mostly air-sensitive compounds which could not be characterized by the magnetic susceptibility.

通过单核和双核金属配合物与桥接配体的结合，制备了具有零、一、二、三维组合的新型磁性配位化合物。通过磁化率的温度依赖性、红外光谱和漫反射光谱以及单晶x射线晶体学对这些化合物进行了表征。4,4′-二硫化物与单核金属配合物反应生成由菱形单元、锯齿形链和锌（II）、锰（II）、钴（II）和镍（II）环化合物组成的一维配位聚合物。该桥接配体与铜（II）羧酸盐反应形成具有重复菱形或多孔蜂窝状结构的一维配位聚合物，表现出反铁磁行为。根据反应条件的不同，双核羧酸钌与N， N'-双齿配体结合可形成四核和一维多核配合物。与八氰钨酸盐，一，二，三维组装得到，这些化合物显示铁磁行为。氰基配体提供了大多数不能用磁化率表征的气敏化合物。

项目成果

Mono-, Di-and Polymeric Copper(II) Complexes with Diclofenic Acid (NSAID Drug), Structures, Spectral and Magnetic Properties

单、二和聚合铜 (II) 与双氯芬酸（NSAID 药物）的配合物、结构、光谱和磁性

• 发表时间: 2005
• 期刊: Advances in Coordination, Bioinorganic and Inorganic Chemistry
• 作者: Kazutaka;Kasuga;Ajay K. Sah;Merii Kato;Misaki Nakai;Merii Kato;Merii Kato;Masahiro Mikuriya;Dariusz Matoga;Dusan Miklos;Ajay K.Sah;Merii Kato;Misaki Nakai;Merii Kato;Merii Kato;Masahiro Mikuriya;Dariusz Matoga;Dusan Miklos;Merii Kato;Merii Kato;Merii Kato;Masahiro Mikuriya;Dariusz Matoga;Dusan Miklos;Dong-Il Kim;Ryo Horikoshi;Ryo Horikoshi;Hiroshi Sakiyama;Ryo Horikoshi;S.Lorinc;D.Yoshioka;D.Yoshioka;M.Mikuriya;Dariusz Matoga;Masahiro Mikuriya;Dong-Il Kim;Ryo Horikoshi;Ryo Horikoshi;Hiroshi Sakiyama;Ryo Horikoshi;S.Lorinc
• 通讯作者: S.Lorinc

Adduct complexes of ruthenium(II,III) propionate dimmer with pyridyl nitroxides

丙酸钌(II,III)二聚体与吡啶基硝基氧的加合物

• 发表时间: 2005
• 期刊: Polyhedron 24・16-17
• 作者: S.Lorinc;M.;D.Yoshioka;D.Yoshioka;M.Mikuriya;D.Matoga;Y.Mikata;M.Mikuriya
• 通讯作者: M.Mikuriya

Synthesis and Characterization of Polynuclear Chain and Tetranuclear Complexes of Mixed-Valent Ruthenium(II, III) Pivalate with N,N'-Didentate Ligands

混合价新戊酸钌(II, III)与N,N-二齿配体的多核链和四核配合物的合成与表征

• 发表时间: 2004
• 期刊: Bulletin of the Chemical Society of Japan 77・12
• 作者: D.Yoshioka;M.Mikuriya;M.Handa
• 通讯作者: M.Handa

Supramolecular isomerism in self-assembled complexes from 4,4'-dipyridyl disulfide and M(hfac)2: Coordination polymers (M = Mn) and metallamacrocycles (M = Co, Ni)

• DOI: 10.1021/cg0499109
• 发表时间: 2005
• 期刊: Crystal Growth & Design
• 影响因子: 3.8
• 作者: R. Horikoshi;T. Mochida;and Makoto Kurihara;M. Mikuriya

Synthesis and characterization of 6-(p-chlorobenzoyl)-5,7,12,14-tetramethyl-benzo[b]-1,4,8,11-tetraazacyclo[14] tetradecinato(2-)nickel(II)

6-(对氯苯甲酰基)-5,7,12,14-四甲基-苯并[b]-1,4,8,11-四氮杂环[14]十四(2-)镍(II)的合成与表征

• 发表时间: 2005
• 期刊: Inorg. Chim. Acta 358
• 作者: Kazutaka;Kasuga;Ajay K. Sah;Merii Kato;Misaki Nakai;Merii Kato;Merii Kato;Masahiro Mikuriya;Dariusz Matoga;Dusan Miklos;Ajay K.Sah;Merii Kato;Misaki Nakai;Merii Kato;Merii Kato;Masahiro Mikuriya;Dariusz Matoga;Dusan Miklos;Merii Kato;Merii Kato;Merii Kato;Masahiro Mikuriya;Dariusz Matoga;Dusan Miklos;Dong-Il Kim
• 通讯作者: Dong-Il Kim