Solvation and cluster structure of ionic liquids

我们研究了离子液体中分子氧的扩散和三重态的弛豫，离子液体中的转动扩散及其分数Stokes-Einstein-Debye定律的分析，蒸发离子液体的低温氖矩阵隔离FTIR光谱，气相中1：1阴阳离子对的几何结构，基于咪唑和吡啶阳离子的蒸发离子液体的电子光谱，以及3-丁基-1-甲基-2-苯基偶氮咪唑的室温光致变色性。

We have carried out research on diffusion of molecular oxygen in ILs and the relaxation of triplet states, rotational diffusion in ILs and their analysis by a fractional Stokes-Einstein-Debye Law, cryogenic neon matrix-isolation FTIR spectroscopy of evaporated ILs, and geometrical structure of cation-anion 1:1 pair in the gas phase, the electronic spectra of vaporized ILs based on imidazolium and pyridinium cations, and photochromism of 3-butyl-1-methyl-2- phenylazoimidazolium in room temperature.