Development of New Surface Finishing Technology Using Ionic Liquids

利用离子液体开发新型表面处理技术

• 批准号: 17073016
• 负责人: KATAYAMA Yasushi
• 金额: $ 24.7万
• 依托单位: Keio University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research on Priority Areas
• 财政年份: 2005
• 资助国家: 日本
• 起止时间: 2005 至 2009
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-17073016/
• 关键词: イオン液体; 電気化学; めっきプロセス; ナノ粒子; パラジウム; ニッケル; 電析; フェロセン; 拡散係数; 電荷移動速度; EQCM; スズ; 銀; 室温イオン液体; 表面処理; めっき; 水素; コバルト; 鉄

Electrochemical reactions of some metal ions have been investigated in ionic liquids, in order to develop a new technology for depositing metals, which are valuable in industry. Mobility of metal ions was found to be slow reflecting the high viscosity of ionic liquids. Reaction rates of metal ions were also slow due to slow dynamics of ionic liquids. Silver, tin, nickel, and palladium were successfully deposited from the ionic liquids.

本文研究了一些金属离子在离子液体中的电化学反应，旨在开发一种具有工业应用价值的金属沉积新技术。金属离子的迁移率被发现是缓慢的，反映了离子液体的高粘度。由于离子液体的缓慢动力学，金属离子的反应速率也很慢。从离子液体中成功地沉积了银、锡、镍和钯。

项目成果

Electrochemical Behavior of Ni(II)/Ni in 1-Butyl-1-methylpyrrolidinium Bis(trifluoromethylsulfonyl)amide Room-Temperature Ionic liquid

Ni(II)/Ni在1-丁基-1-甲基吡咯烷鎓双(三氟甲基磺酰基)酰胺室温离子液体中的电化学行为

• 发表时间: 2009
• 作者: Y. -L. Zhu;Y. Kozuma;Y. Katayama;T. Miura
• 通讯作者: T. Miura

EQCM measurement of Sn(II)/Sn reaction in imide-type room-temperature ionic liquid

EQCM 测量酰亚胺型室温离子液体中 Sn(II)/Sn 反应

• 发表时间: 2008
• 作者: N. Serizawa;N. Tachikawa;Y. Katayama;T. Miura
• 通讯作者: T. Miura

Photoelectrochemical Behavior of a Single Crystal n-TiO2 Electrode in Ionic Liquids

单晶 n-TiO2 电极在离子液体中的光电化学行为

• 发表时间: 2008
• 作者: S. Koshizawa;Y. Katayama;T. Miura
• 通讯作者: T. Miura

Photoelectrochemical Behavior of a Single Crystal n-Ti02 Electrode in Ionic Liquids

单晶 n-TiO2 电极在离子液体中的光电化学行为

• 发表时间: 2008
• 作者: S. Koshizawa;Y. Katayama;and T. Miura
• 通讯作者: and T. Miura

Electrodeposition of cobalt from an imide-type room-temperature ionic liquid

• DOI: 10.1149/1.2768298
• 发表时间: 2007-01-01
• 期刊: JOURNAL OF THE ELECTROCHEMICAL SOCIETY
• 影响因子: 3.9
• 作者: Katayama, Yasushi;Fukui, Ryuta;Miura, Takashi
• 通讯作者: Miura, Takashi