Study on polynuclear species not supported by metal-metal bonds
Study on polynuclear species not supported by metal-metal bonds
批准号:
18065009
负责人:
AKITA Munetaka
金额:
$20.74万
依托单位国家:
日本
项目类别:
Grant-in-Aid for Scientific Research on Priority Areas
财政年份:
2006
资助国家:
日本
项目状态:
已结题
起止时间:
2006 至 2009
中文摘要
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英文摘要
Polynuclear species are expected to display chemical properties, which cannot be realized by mononuclear species. In this study we focus on catalytic activity induced by cooperation of the component metal centers. We have found that dinuclear species containing a [Ru(bipy)_3]^<2+>-like unit as the light-harvesting unit and a Pd center as the catalytic transformation center show catalytic activity for dimerizaton and polymerization of olefins, which is remarkably enhanced by irradiation of visible light..
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p-Diethynylbenzene-based molecular wires, Fe-CC-p-C6H2X2-CC-Fe : Synthesis, substituent effects and unexpected formation of benzodifuran complex
对二乙炔基苯分子线,Fe-CC-p-C6H2X2-CC-Fe:苯并二呋喃配合物的合成、取代效应和意外形成
DOI:
--
发表时间:
2009
期刊:
J. Organomet. Chem 694
影响因子:
--
作者:
[松浦有美, 田中裕也, 穐田宗隆]
通讯作者:
穐田宗隆
Supercritical Fluids in Organic Chemistry
有机化学中的超临界流体
DOI:
--
发表时间:
2007
期刊:
影响因子:
--
作者:
[Y. Tanaka, T. Ozawa, A. Inagaki, M. Akita, Takao Ikariya]
通讯作者:
Takao Ikariya
Organometallic Chemistry of Polycarbon Species : From Cluster to Mole-cular Devices
多碳物质的有机金属化学:从簇到分子器件
DOI:
--
发表时间:
2008
期刊:
Dalton Transactions
影响因子:
4
作者:
[穐田宗隆, 小池隆司]
通讯作者:
小池隆司
C-C Coupling of Permetallated Ethene, (μ4-C=C)Ru_2(FeCp^*)_2(CO)_<10>, with Alkynes, and Isolation of Labile MeCN Adduct, (μ4-C=C)Ru_2(FeCp^*)_2(CO)_8(NCMe)_2
全金属化乙烯 (μ4-C=C)Ru_2(FeCp^*)_2(CO)_<10> 与炔烃的 C-C 偶联,以及不稳定 MeCN 加合物的分离 (μ4-C=C)Ru_2(FeCp^* )_2(CO)_8(NCMe)_2
DOI:
--
发表时间:
2007
期刊:
Organometallics 26
影响因子:
--
作者:
[G.Higashihara, M.Terada, A.Inagaki, M.Akita]
通讯作者:
M.Akita
Organometallic Chemistry and Catalysis in Water
水中有机金属化学和催化
DOI:
--
发表时间:
2007
期刊:
影响因子:
--
作者:
[小宮, ら, S. Komiya]
通讯作者:
S. Komiya
共 62 条
study on metal complexes with extended pi-conjugated system toward molecular circuits
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批准号:22350026
-
项目类别:Grant-in-Aid for Scientific Research (B)
-
资助金额:$12.15万
-
财政年份:2010
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负责人:AKITA Munetaka
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依托单位:
Organometallic chemistry of carbon allotropes: extension to two-dimensional systems and applications to highly functionalized systems.
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批准号:15350032
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项目类别:Grant-in-Aid for Scientific Research (B)
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资助金额:$9.6万
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财政年份:2003
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负责人:AKITA Munetaka
-
依托单位:
Elucidation of the relationship between the structure and the reactivity of transition metal dioxygen complexes
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批准号:11228201
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项目类别:Grant-in-Aid for Scientific Research on Priority Areas
-
资助金额:$27.07万
-
财政年份:1999
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负责人:AKITA Munetaka
-
依托单位: