Group 13 Mixed Halide-Hydride and Rare Earth Complexes - New Selective Chiral Hydridic or Low Valent Reducing Agents

第 13 族混合卤化物-氢化物和稀土配合物 - 新型选择性手性氢化物或低价还原剂

• 批准号: DP0558562
• 负责人: A/Prof Marcus Cole
• 金额: $ 17.98万
• 依托单位: The University of New South Wales
• 依托单位国家: 澳大利亚
• 项目类别: Discovery Projects
• 财政年份: 2005
• 资助国家: 澳大利亚
• 起止时间: 2005-01-01 至 2009-12-31
• 项目状态: 已结题
• 来源: https://dataportal.arc.gov.au/RGS/Web/Grants/DP0558562
• 关键词: Group; 13; Mixed; Halide; Hydride

This project will make a landmark contribution to two areas of metallohydride chemistry. Both studies will utilise and develop metals that have traditionally been mined and exported from these shores while concurrently imported as value added products at vastly inflated cost. This research will identify knock-on applications in order to stem this financial bias. The new paths to rare earth (= Ln) hydrides will have broad industrial appeal, particularly for new materials, where, like similar group 13 materials, they may be used in the deposition of Ln films or even as precursors to superconducting solids. It is anticipated industrial collaboration will ensue. Australia will be promoted as a developer and innovator of frontier technologies.

该项目将对金属氢化物化学的两个领域做出里程碑式的贡献。这两项研究都将利用和开发传统上从这些海岸开采和出口的金属，同时以大幅膨胀的成本作为增值产品进口。这项研究将确定连锁应用，以遏制这种金融偏见。稀土（= Ln）氧化物的新途径将具有广泛的工业吸引力，特别是对于新材料，与类似的13族材料一样，它们可以用于沉积Ln薄膜，甚至作为超导固体的前体。预计工业合作将随之而来。澳大利亚将被提升为前沿技术的开发者和创新者。