Development of high ion conductive glass-ceramics for realizingall-solid-state batteries

开发高离子导电玻璃陶瓷以实现全固态电池

• 批准号: 21246098
• 负责人: TATSUMISAGO Masahiro
• 金额: $ 29.12万
• 依托单位: Osaka Prefecture University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (A)
• 财政年份: 2009
• 资助国家: 日本
• 起止时间: 2009 至 2012
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-21246098/
• 关键词: 固体電解質; 硫化物電解質; ガラス; ガラスセラミックス; 全固体電池; リチウム電池; リチウムイオン; イオン伝導

Glass-ceramic Li_2S-P_2S_5 electrolytes with a high conductivity of over 5×10^<-3>S cm^<-1>at room temperature were prepared by optimizing preparation conditions of mother glasses, crystallization conditions, glass compositions. Chemical stability of sulfide electrolytes under exposure to air atmosphere was evaluated. The electrolyte with 75 mol% Li_2S showed the highest chemical stability in the binary system Li_2S-P_2S_5. Furthermore, the addition of metal oxides as H_2S absorbents was effective in reducing H_2S gas generation from the electrolytes. All-solid-state In / LiCoO_2 cells with the prepared electrolytes operated as secondary batteries with good cyclability.

通过<-3><-1>对母玻璃制备条件、晶化条件、玻璃组成的优化，制备出室温电导率大于5×10^ S cm^2的Li_2S-P_2S_5微晶玻璃电解质。评价了硫化物电解质在暴露于空气气氛下的化学稳定性。在Li_2S-P_2S_5二元体系中，Li_2S含量为75 mol%时，电解质的化学稳定性最高。此外，金属氧化物作为H_2S吸收剂的加入能有效地减少电解液中H_2S气体的产生。用所制备的电解质制成的全固态In / LiCoO_2电池作为二次电池运行，具有良好的循环性能。

项目成果

Synthesis of NiS-carbon fiber composites in high-boiling solvent to improve electrochemical performance in all-solid-state lithium secondary batteries

• DOI: 10.1016/j.electacta.2012.07.088
• 发表时间: 2012-11
• 期刊: Electrochimica Acta
• 影响因子: 6.6
• 作者: K. Aso;A. Hayashi;M. Tatsumisago

Interfacial Observation between LiCoO_2 Electrode and Li_2S-P_2S_5 Solid Electrolytes of All-Solid-State Lithium Secondary Batteries Using Transmission Electron Microscopy

全固态锂二次电池LiCoO_2电极与Li_2S-P_2S_5固体电解质的界面透射电子显微镜观察

• 发表时间: 2010
• 期刊: Chem.Mater. 22
• 作者: 大場;大沼;Koppoju;吹田啓一郎,真鍋義貴,佐藤篤司,津嘉田敬章,田中剛,他1名;A.Sakuda
• 通讯作者: A.Sakuda

Characterization of Solid Electrolytes Prepared from Ionic Glass and Ionic Liquid for All-Solid-State Lithium Batteries

离子玻璃和离子液体制备全固态锂电池固体电解质的表征

• DOI: 10.1016/j.ssi.2010.07.011
• 发表时间: 2011
• 期刊: Solid State Ionics
• 影响因子: 3.2
• 作者: K. Suita;Y. Manabe;K. Takatsuka;T. Tanaka and T. Tsukada;中島直人;A.Hayashi
• 通讯作者: A.Hayashi

Characterization of Hybrid Electrolytes Prepared from the Li_2S-P_2S_5 Glasses and Alkanediols

Li_2S-P_2S_5玻璃和烷二醇制备的混合电解质的表征

• DOI: 10.1016/j.ssi.2009.12.006
• 发表时间: 2011
• 期刊: Solid State Ionics
• 影响因子: 3.2
• 作者: K. Suita;Y. Manabe;K. Takatsuka;T. Tanaka and T. Tsukada;宮原淳也・李洪源・松永信博;A.Hayashi
• 通讯作者: A.Hayashi

Preparation of amorphous Li4SiO4–Li3PO4 thin films by pulsed laser deposition for all-solid-state lithium secondary batteries

• DOI: 10.1016/j.ssi.2010.12.001
• 发表时间: 2011-02
• 期刊: Solid State Ionics
• 影响因子: 3.2
• 作者: Yuki Sakurai;A. Sakuda;A. Hayashi;M. Tatsumisago