Aminoimidazolin-2-imine and the 1,8-disubstituted naphthalene scaffold in the chemistry of the elements aluminium und boron

元素铝和硼化学中的氨基咪唑啉-2-亚胺和 1,8-二取代萘支架

• 批准号: 520572639
• 负责人: Dr. René Frank
• 金额: --
• 依托单位: Institut für Anorganische und Analytische Chemie
• 依托单位国家: 德国
• 项目类别: Research Grants
• 资助国家: 德国
• 项目状态: 未结题
• 来源: https://gepris.dfg.de/gepris/projekt/520572639?language=en
• 关键词: Aminoimidazolin; imine; disubstituted; naphthalene; scaffold

The project deals with the recently developed ligand class of aminoimidazoline-2-imines, which are employed in the complexation of the elements boron and aluminium. Based on previous findings from our group the archetypal representatives of iminoboranes with the parent B=NH motif will be synthesized and characterized by follow-up chemistry. The same ligand class also lents itself for the preparation of low valent Al(I) compounds (alumylenes), the chemistry of which will be explored. In a second, separate project part the elements aluminium and boron will be connected. The 1,8-disubstituted napththalene entity is presented in the generation of electron precise Al-B bonds, including the elaboration of further chemistry.

该项目涉及最近开发的氨基咪唑啉-2-亚胺配体类，其用于元素硼和铝的络合。根据我们小组之前的发现，将合成具有母体 B=NH 基序的亚氨基硼烷的原型代表，并通过后续化学进行表征。相同的配体类别也适用于制备低价 Al(I) 化合物（亚铝烯），其化学性质将被探索。在第二个单独的项目部分中，铝和硼元素将被连接。 1,8-二取代萘实体在电子精确的 Al-B 键的生成中呈现，包括进一步化学的阐述。