Short Range Order in Interstitial Alloys.
Short Range Order in Interstitial Alloys.
批准号:
61550472
负责人:
YAMAGUCHI Sadae
金额:
$1.02万
依托单位:
依托单位国家:
日本
项目类别:
Grant-in-Aid for General Scientific Research (C)
财政年份:
1986
资助国家:
日本
项目状态:
已结题
起止时间:
1986 至 1988
中文摘要
1)通过弹性中子扩散散射测量,确定了TiO_(3.32)&gT;单晶中氧排列的短程有序参数。通过实验强度与理论强度的最小二乘拟合,从总的漫射强度中分离出短程有序项。氧原子的第一、第三和第五邻原子排列更倾向于被空位包围,而不是被氧原子包围。而氧原子优先占据第二和第四近邻位置。2)通过弹性中子扩散散射测量,确定了单晶中氦排列的短程有序参数。在钒晶格的四面体间隙位置的第一、第二和第三邻位处,空位-氚原子对具有择优构型,而在第四邻位处,则出现了氘-氚原子对的择优构型。3)用中子小角散射研究了Nb-N和Ta-N合金中氮原子的局域原子排列。低Q区的扩散强度揭示了氮原子碎屑的存在。
英文摘要
1) Short-range order parameters for oxygen arrangement in single crystal of Tio_<3.32> were determined by measurements of elastic neutron diffuse scattering. The short range order term were separated from the total diffuse intensity by least squares fit of the experimental intensity with a theoretical one. The first-, third and fifth-neighbor atomic arrangement of the oxygen atom has a preference to be surrounded by vacancies rather than by oxygen atoms. While, the second- and fourth-neighbor site are occupied preferentially by oxygen atoms.2) Short-range order parameters for deuterium arrangement in single crystal of VD_<0.81> were determined by measurements of elastic neutron diffuse scattering. The preferential configrations of vacancy-deuterium atom pair are found at first-, second-, and thirdneighbors of tetrahedral interstitial sites of the host vanadium lattice whereas the deuterium-deuterium atom pairs occur at the fourth neighbors. These features are similar to those in the ordered structure below T_c.3) Local atomic arrangements of nitrogen atoms in Nb-N and Ta-N alloys have been studied by neutron small angle scattering. The diffuse intensity of low Q region revealed the existence of the nitorogen atom clasters.
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通讯作者:
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依托单位: