A Predictive Theory of Kinetic Demixing in Engineering Ceramics

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Technological advances bring demands for new engineering ceramics and the improvement of existing ones. The properties of engineering ceramics are critically dependent on the composition and distribution of atomic components. However, separation or demixing of the components occurs in-service at high temperatures as a result of stress, electric fields or oxygen gradients. Demixing causes a major loss of performance and longevity. This Project will develop a robust and versatile theory of demixing to enhance longevities of engineering ceramics. It will also guide the deliberate manipulation of demixing to generate novel compositionally-graded engineering ceramics having new properties of technological interest.