Synthesis of Solar Energy Storage-Exchange Polymers

太阳能储存交换聚合物的合成

• 批准号: 03650752
• 负责人: NISHIKUBO Tadatomi
• 金额: $ 1.22万
• 依托单位: Kanagawa University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for General Scientific Research (C)
• 财政年份: 1991
• 资助国家: 日本
• 起止时间: 1991 至 1992
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-03650752/
• 关键词: Solar Energy Storage-Exchange; NBD Residues; Polymer Synthesis; Cationic polymerization; Polymer Reaction; Polycondensation; PGMA; ポリアミド; 光ー熱変換機能高分子; 選択カチオン重合; 機能性モノマ-; ノルボルナジエン残基; クワドリシクラン残基; 光反応性; 蓄熱量

This research project investigates the synthesis of solar energy storage - exchange polymers bearing norbornadiene (NBD) moieties, and evaluates the photochemical reactivity and the energy storage property of the resultingpolymers.(1) New photoresponsive polymers bearing norboenadiene moieties were synthesized by the cationic homo- and co-polymeri-zation of 2-[[(3-phenyl-2, 5-norbornadienyl)-2-carbonyl] oxy ethy vinyl ether], and the photochemical reaction the pendant NBD moiety in the polymer and catalytic reversion of the resulting pendant quadricyclane (QC) group in the polymer were investigated.(2) New photoresponsive polyamides were prepared by the condensation reaction of 2, 5-norbornadiene-2, 3-dicarboxylic acid dichloride (NBDC) with various diamines, and the photochemical reactivity and the energy storage property were evaluated in the film state.(3) New chalcone type NBD compound was prepared, and then the polymer having chalcone type NBD residue, which has excellent photochemical reactivity, was synthesized by the reaction of the above compound with poly(p-chloromethylstyrene) using phase transfer catalyst.

本课题研究了含降冰片二烯（NBD）基团的太阳能储能交换聚合物的合成，并对所得聚合物的光化学反应性和储能性能进行了评价。(1)采用2-[[（3-苯基- 2,5 -降龙骨二烯基）-2-羰基]氧乙基乙烯醚]阳离子同聚和共聚的方法合成了含去甲二烯基团的新型光响应聚合物，并研究了聚合物中悬垂的NBD基团的光化学反应和聚合物中悬垂的四环（QC）基团的催化还原反应。(2)采用2,5 -降冰片二烯- 2,3 -二羧酸二氯（NBDC）与多种二胺缩合反应制备了新型光响应聚酰胺，并对其在薄膜状态下的光化学反应性和储能性能进行了评价。(3)制备了新的查尔酮型NBD化合物，并利用相转移催化剂将该化合物与聚对氯甲基苯乙烯反应，合成了具有良好光化学反应活性的查尔酮型NBD残留物聚合物。

项目成果

T.Nishikubo, A.Kameyama, K.Kishi, and C.Hijikata: "Synthesis of New Photoresponsive Polymers Bearing Norbornadiene Moiety by Selective Cationic Polymerization of 2{[(3-Phenyl-2, 5- norbornadienyl)-2-carbonyl}oxy} ethyl Vinyl Ether and Photochemical Reacti

T.Nishikubo、A.Kameyama、K.Kishi 和 C.Hijikata：“通过 2{[(3-苯基-2, 5-降冰片二烯基)-2-羰基} 的选择性阳离子聚合合成带有降冰片二烯部分的新型光响应聚合物”

岸 克彦,亀山 敦,西久保 忠臣: "高分子側鎖のエポキシ基とノルボルナジエンカルボン酸クロリドとの付加反応による光エネルギー蓄積・変換高分子の合成とその光反応" 高分子論文集. 50. 137-145 (1993)

Katsuhiko Kishi、Atsushi Kameyama、Tadaomi Nishikubo：“光能存储/转换聚合物的合成及其通过聚合物侧链中的环氧基团与降冰片二烯甲酰氯之间的加成反应的光反应”，Kobunshi Proceedings。 50. 137-145 (1993)。

K.Kishi, A.Kameyama, and T.Nishikubo: "Synthesis of Solar Energy Storage-Exchange Polymer Bearing Chalcone Type NBD Residue and Evaluation of Photochemical Properties of the Resulting Polymer" Kobunsahi Ronbunshu.

K.Kishi、A.Kameyama 和 T.Nishikubo：“带有查尔酮型 NBD 残留物的太阳能储存交换聚合物的合成以及所得聚合物的光化学性质的评估”Kobunsahi Ronbunshu。

T.Nishikubo: "Synthesis of Polymers Bearing Pendant Norbornadiene Moieties by Addition Reaction of Poly(glycidyl methacrylateーcoーmethyl methacryーlate)with 2,5ーNorbornadieneー2ーCarboxylic Acids" J.Polym.Sci.Part A:Polrm.Chem.Ed.

T.Nishikubo：“通过聚（甲基丙烯酸缩水甘油酯-共-甲基丙烯酸甲酯）与 2,5-降冰片二烯-2-羧酸的加成反应合成带有降冰片二烯侧基的聚合物”J.Polym.Sci.A 部分：Polrm.Chem .Ed.