Multi-dimentional Analysis of Highly Specific Organic Reactions Governed by the Combinal Influence of Functional Groups

官能团综合影响下的高特异性有机反应的多维分析

• 批准号: 04303002
• 负责人: SUZUKI Hitomi
• 金额: $ 15.62万
• 依托单位: KYOTO UNIVERSITY
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Co-operative Research (A)
• 财政年份: 1992
• 资助国家: 日本
• 起止时间: 1992 至 1993
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-04303002/
• 关键词: Substituent effect; Heteroatom Compounds; Stereochemistry; Asymmetric Synthesis; Kinetics; Photochemical reaction; Electron transfer; Reaction intermediate

Specificity in organic reactions, one of the most important research subjects of current organic chemistry, has been investigated systematically under the name of the title joint project by twenty-eight chemists of a wide variety of speciality backgrounds. The selected experts were devided into three project teams of comparative size ; the first team was mainly concerned with the problems on the enhancement of specificity and reactivity by organic functional groups ; the second one was devoted to the analysis of the relationship between reactivity and electronic requirements, and the last one dealt with the high specificity arising from some functionalized reactive intermediate. The project has brought a great success, more than 460 original papers being published in prestigeous international journals during the given period of the joint studies. Major part of the fruitful results has been presented by the members of each team at two open meetings held in Kyoto on Dec. 4-5, 1993 and Dec. 17-18, 1994.

有机反应的特异性是当前有机化学中最重要的研究课题之一。选定的专家被分成三个规模相当的项目小组;第一个小组主要关注有机官能团增强特异性和反应性的问题;第二个小组致力于分析反应性与电子需求之间的关系;最后一个小组处理由某些官能化反应中间体引起的高特异性。该项目取得了巨大成功，在联合研究的特定时期内，有460多篇原创论文在国际期刊上发表。1993年12月4日至5日和1994年12月17日至18日在京都举行的两次公开会议上，每个小组的成员都介绍了成果的大部分。

项目成果

Mitsuo Kira: "p-and m-Phenylenebis[trifluoro(phenyl)silicates] and Related Monosilicates" Chem.Lett.1859-1862 (1993)

Mitsuo Kira：“对-和间-亚苯基双[三氟(苯基)硅酸盐]和相关的单硅酸盐”Chem.Lett.1859-1862 (1993)

Hideo Tomioka: "Formation of Heptafulvene in Reaction of (Methoxycarbonyl) phenyl carbene in the Gas Phases" J.Am. Chem. Soc.58. 4196-4197 (1993)

Hideo Tomioka：“（甲氧基羰基）苯基卡宾在气相中反应形成庚富烯”J.Am.

Mitso Kira: "p-and m-phenylenebis (tri-fluoro (phenyl) silicates) and related Monosilicates" Chem. Lett.1859-1862 (1993)

Mitso Kira：“对-和间-亚苯基双（三氟（苯基）硅酸盐）和相关的单硅酸盐”Chem。

Hideo Tomioka: "Formation of Heptafulvene in Reaction of [(Methoxycarbonyl)]phenylcarbene in the Gas Phases" J.Am.Chem.Soc.58. 4196-4197 (1993)

Hideo Tomioka：“[(甲氧基羰基)]苯基卡宾在气相中反应形成庚富烯”J.Am.Chem.Soc.58。

Mitsuo Kira: "p- and m-Phenylenebis[trifluoro(phenyl)silicates]and Related Monosilicates" Chem.Lett.1859-1862 (1993)

Mitsuo Kira：“对-和间-亚苯基双[三氟(苯基)硅酸盐]和相关的单硅酸盐”Chem.Lett.1859-1862 (1993)