Development of (X,eX) Spectroscopy
Development of (X,eX) Spectroscopy
批准号:
04403003
负责人:
UDAGAWA Yasuo
金额:
$11.14万
依托单位:
依托单位国家:
日本
项目类别:
Grant-in-Aid for General Scientific Research (A)
财政年份:
1992
资助国家:
日本
项目状态:
已结题
起止时间:
1992 至 1994
中文摘要
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英文摘要
In Compton scattering experiments, monochromatic X-ray photons are inelastically scattered, and scattered X-ray photons are detected as a function of direction and energy. In (X,eX) spectroscopy, in addition to X-ray photons, coincident recoil electrons are measure also as a function of energy and direction. Then, by the use of momentum coservation and energy conservation, the initial electronic state can completely described. Although pointed out in earlier times, (X,eX) signal has never been observed because of experimental difficulties. In order for this goal to be achieved, excitation X-rays should be strong, scattered X-rays should be efficiently collected, and recoil electron should be discriminated from electrons from different origin, ex.photoelectron. In this study, efficient X-ray spectrometera and an electron analyzer are developed in order to observe (X,eX) phenomenon.A monochromator having a spherically bent Si (440) crystal and a spectrometer having a singly bent graphite (004) crystal were constructed. By the use of these, very weak X-ray Raman scattering was observed (Reference 1). Then, a single spherical electrostatic analyzer was constructed, which consists of an inner sphere of 64 mm in diameter and an oute sphere of 86 mm in diameter. The resolution was 2 eV as expected, and (e, 2e) phenomena which is an electron analogure of (X,eX) were observed (submitted for publication). By combining these elements (X,eX) measurements were carried out and coincident signals were observed. They might, however, originate from photoelectron, and we are still trying to make it sure whether they are (X,eX) signals or not.
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Y.Udagawa,H.Hayashi,K.Tohji and T.Mizushima: "X-Ray Resonant Raman Spectra of Several Copper Compounds" J.Phys.Soc.Jpn.63. 1713-1720 (1994)
Y.Udakawa、H.Hayashi、K.Tohji 和 T.Mizushima:“几种铜化合物的 X 射线共振拉曼光谱”J.Phys.Soc.Jpn.63。
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通讯作者:
宇田川康夫: "X線吸収微細構造" 学会出版センター, 222 (1993)
宇田川康夫:《X射线吸收精细结构》学会出版中心,222(1993)
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H.Hayashi,K.Tohji,Y.Udagawa,and A.Ueno.: "Small-Angle X-Ray Scattering Study on the Growth of Metal Silicate Polymers" Bull.Chem.Soc.Jpn.66. 1024-1027 (1993)
H.Hayashi、K.Tohji、Y.Udakawa 和 A.Ueno.:“金属硅酸盐聚合物生长的小角度 X 射线散射研究”Bull.Chem.Soc.Jpn.66。
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水嶋生智、宇田川康夫: "「金属アルコキシドを用いる触媒調製」(上野晃史他編)" アイピーシー, 17 (1993)
Ikutomo Mizushima、Yasuo Udakawa:“‘使用金属醇盐制备催化剂’(由 Akira Ueno 等人编辑)”IPC,17 (1993)
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宇田川 康夫,田路 和幸,水嶋 生智,林 久史: "種々の同化合物のX線共鳴ラマンスペクトル" 豊田研究報告. 45. 9-18 (1992)
Yasuo Udakawa、Kazuyuki Taji、Ikutomo Mizushima、Hisashi Hayashi:“各种相同化合物的 X 射线共振拉曼光谱”丰田研究报告 45. 9-18 (1992)。
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共 14 条
A development of site-selective, valence-selective, and spin-selective XAFS spectroscopy by inelastic x-ray scattering
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批准号:15205002
-
项目类别:Grant-in-Aid for Scientific Research (A)
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资助金额:$27.29万
-
财政年份:2003
-
负责人:UDAGAWA Yasuo
-
依托单位:
Wavefuntion in Momentum Space and Molecular Recognition
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批准号:13440205
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项目类别:Grant-in-Aid for Scientific Research (B)
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资助金额:$7.74万
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财政年份:2001
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负责人:UDAGAWA Yasuo
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依托单位:
X-ray inelastic scattering and radiation chemistry
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批准号:11694053
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项目类别:Grant-in-Aid for Scientific Research (C)
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资助金额:$0.77万
-
财政年份:1999
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负责人:UDAGAWA Yasuo
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依托单位:
Orbital pattern imaging
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批准号:10304046
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项目类别:Grant-in-Aid for Scientific Research (A)
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资助金额:$21.7万
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财政年份:1998
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负责人:UDAGAWA Yasuo
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依托单位:
A development of absorption spectra for wide energy region by inelastic x-ray scattering
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批准号:10554029
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项目类别:Grant-in-Aid for Scientific Research (B)
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资助金额:$7.74万
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财政年份:1998
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负责人:UDAGAWA Yasuo
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依托单位:
A study of wavefunction and chemical bonding by (e, 2e) electron momentum spectroscopy
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批准号:07404032
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项目类别:Grant-in-Aid for Scientific Research (A)
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资助金额:$10.56万
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财政年份:1995
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负责人:UDAGAWA Yasuo
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依托单位:
A Development of Fluorescent Detection in Laboratory EXAFS
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批准号:01850174
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项目类别:Grant-in-Aid for Developmental Scientific Research (B).
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资助金额:$1.79万
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财政年份:1989
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负责人:UDAGAWA Yasuo
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依托单位:
A Development of Laboratory EXAFS Spectrometer
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批准号:61890012
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项目类别:Grant-in-Aid for Developmental Scientific Research
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资助金额:$4.74万
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财政年份:1986
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负责人:UDAGAWA Yasuo
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依托单位: