JOINT STUDY ON THE SOLAR-DRIVEN CHEMICAL HEAT PUMP

太阳能化学热泵联合研究

• 批准号: 06044074
• 负责人: KAMEYAMA Hideo
• 金额: $ 7.94万
• 依托单位: TOKYO UNIV.OF AGRICULTURE AND TECHNOLOGY
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for international Scientific Research
• 财政年份: 1994
• 资助国家: 日本
• 起止时间: 1994 至 1995
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-06044074/
• 关键词: Solar energy utilization; chemical heat pump; plate-type catalyst; dehydrogenation reaction; acetone; 2-propanol; liquid film reactor; process simulation

This is a project for a international cooperative research program between Japan and USA financially supported by the Ministry of Education, Science, Sports and Culture in Japan. This project was two years program from 1994 fiscal year to develop a process to storage the low-level heat under 80 ﾟC and to upgrade it to the highlevel heat around 200 ﾟC using solar thermal energy as the primary energy input. The major objective of the program was to investigate a process feasibility of a solar-driven chemical heat pump, which was combined a chemical heat pump system being developed in Japan with solar panel and process interface technologies being developed in USA.This project has combined many isolated research activites conducted in the two countries and made effective use of them by cooperative research and sharing of research results. The process proposed in this project has also a big potential for decreasing CO_2 emission into the environment from industries by the energy saving cau … More sed by application to the efficient utilization of huge amounts of low-level heat exhausted from industries. Many technological problems must be solved to improve the thermal efficiency and to apply this system for effective utilization of solar energy. This project was planed to build on the following works already done in the USA and Japan and to make new technologies to overcome a wall of low thermal efficiency and to make realize new type of chemical heat pump using solar energy.1. Solar utilization technologies of solar receivers and control being developed in the USA.2. Chemical heat pump technologies being developed in Japan.3. Technology of plate-type catalyst with high thermal conductivity being developed in Japan.4. New type of unit operations such as plat type catalytic reactor and internal heat integrated distilllation column.5. Energy and Exergy analysis of chemical process by using ASPEN PLUS process simulator installed in each research laboratories.6. New process designs being discussed between USA and Japan.As a conclusion, several key technologies was recommended to be introduced for improving thermal efficiency of this chemical heat pump system. Less

这是一个日本和美国之间的国际合作研究项目，由日本文部科学省资助。该项目是从1994财年开始的两年计划，目的是开发一种工艺，将低水平的热量储存在80ﾟC以下，并使用太阳能作为一次能源输入，将其升级到200ﾟC左右的高水平热量。该计划的主要目标是调查太阳能驱动的化学热泵的工艺可行性，该热泵是将日本正在开发的化学热泵系统与美国正在开发的太阳能电池板和工艺接口技术相结合。该项目结合了两国进行的许多孤立的研究活动，并通过合作研究和研究成果共享有效地利用了这些研究活动。该项目提出的工艺也具有通过节能CAU…减少工业向环境排放二氧化碳的巨大潜力更适用于高效利用从工业中排出的大量低水平热量。要提高太阳能的热效率，实现太阳能的有效利用，必须解决很多技术问题。该项目计划在美国和日本已经完成的工作的基础上，开发新技术，克服热效率低的墙体，实现利用太阳能的新型化学热泵。美国正在开发太阳能接收器的太阳能利用技术和控制。日本正在开发的化学热泵技术。日本正在开发高导热板式催化剂技术。平板式催化反应器、内热集成蒸馏塔等新型装置操作。利用安装在各研究实验室的Aspen plus过程模拟器对化工过程进行能量分析和火用分析。美国和日本正在讨论新的工艺设计。最后，建议引入几项关键技术来提高化学热泵系统的热效率。较少

项目成果

寺井 聡、村田 究、山本協子、亀山秀雄、: "プレート状アルミナ触媒の細孔制御に関する研究" 化学工学論文集. 21. 1069-1074 (1996)

Satoshi Terai、Satoru Murata、Kyoko Yamamoto、Hideo Kameyama：“板状氧化铝催化剂的孔控制研究”化学工程杂志 21. 1069-1074 (1996)。

P.Gastauer,and H.Kameyama: "Combination of the Isopropanol/Acetone/Hydrogen Cycle and the Cyclohexane/Benzene/Hydrogen Chemical Heat Pump" Proceedings of Int.Symposium on Energy,Environmentand Economics,Melbourne,Australia. 1. 150-155 (1995)

P.Gastauer 和 H.Kameyama：“异丙醇/丙酮/氢循环与环己烷/苯/氢化学热泵的组合”能源、环境和经济国际研讨会论文集，澳大利亚墨尔本。

亀山 秀雄: "ニッケル超微粒子の電着法によるプレート状触媒の調製法の研究" 化学工学論文集. 20. 131-133 (1994)

Hideo Kameyama：“超细镍颗粒电沉积制备板状催化剂的研究”化学工程杂志 20. 131-133 (1994)。

P.Gastauer, and H.Kameyama: "Combination of the Isopropanol /Acetone/Hydrogen Cycle and the Cyclohexane/Benzene/Hydrogen Chemical Heat Pump" Proceedings of Int.Symposium on Energy, Environmentand Economics, Melbourne, Australia. 1. 150-155 (1995)

P.Gastauer 和 H.Kameyama：“异丙醇/丙酮/氢循环和环己烷/苯/氢化学热泵的组合”能源、环境和经济国际研讨会论文集，澳大利亚墨尔本。

Hideo Kameyama and Noritoku Kojima: Baifukan. Resources and Energy Recycling, -250 (1996)

龟山秀夫和小岛则德：梅风馆。